DMA(二甲基胺)改性介孔二氧化硅吸附剂对铬酸根阴离子 (CrO42-) 的解吸作用

Septya Anggraini, Budhi Oktavia, Indang Dewata, Fajriah Azra
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摘要

二甲胺修饰介孔二氧化硅是一种用于阴离子交换和阴离子分离的官能团吸附剂。加入胺类化合物的介孔二氧化硅可以用柱法观察二氧化硅对铬酸盐阴离子的吸收能力。对铬酸盐阴离子的吸收率为0.8609 mg/g,吸收率为99.3%。如果吸附过程已经达到最大值,吸附剂表面饱和或不再能够吸附吸附质而发生平衡,则可以继续进行解吸过程。考察这种解吸能力的因素是解吸类型,即盐酸(HCl),其释放的铬酸盐阴离子为0.4061 mg,解吸率为95.3%,最佳浓度为0.1 M HCl,其释放的铬酸盐阴离子为0.4287 mg,解吸率为100%。
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Desorpsi Anion Kromat (CrO42-) dari Adsorben Silika Mesopori Termodifikasi DMA (Dimethylamine)
Mesopore silica modified with dimethylamine is one of the adsorbents used as a functional group for anion exchange and anion separation. Mesopore silica with the addition of amine compounds can be used to see the absorption capacity of silica against chromate anions using the column method. The absorption capacity of the chromate anion is 0.8609 mg/g with an absorption percentage of 99.3%. If the adsorption process has been maximized, the surface of the adsorbent is saturated or no longer able to absorb the adsorbate and equilibrium occurs, it can be continued with the desorption process. The factor used to see this desorption ability is the type of desorption, namely hydrochloric acid (HCl) with a release of 0.4061 mg of chromate anion with a desorption percentage of 95.3% and an optimum concentration of 0.1 M HCl with a release of 0.4287 mg chromate anion with a desorption percentage of 100%.
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