高密度聚乙烯对接熔焊接头的加速热氧化老化和降解机理

IF 2.1 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Mechanics of Time-Dependent Materials Pub Date : 2023-12-29 DOI:10.1007/s11043-023-09655-3
Ying-Chun Chen, Yan-Feng Li, Jie Yang, Yan Xi, Qiang Li, Xiao-li Fan
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引用次数: 0

摘要

高密度聚乙烯(HDPE)管道广泛应用于天然气运输。对熔焊接接头在焊接过程中会熔化和冷却,从而导致机械性能、分子链空间位置微观结构和官能团发生变化。在此,我们通过各种温度梯度下的加速热氧化老化试验来研究高密度聚乙烯对熔焊接接头的老化行为。测量了维卡软化温度、氧化诱导时间和红外光谱,并观察了微观结构。结果表明,随着老化温度的升高,对接熔焊接头的机械和化学性能都有所下降。分析确定了热影响区的分子链交叉机制和焊接连接机制。研究结果有助于理解高密度聚乙烯的老化行为,并为降低对接熔接接头降解造成的风险提供指导。
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Accelerated thermal-oxidative aging and degradation mechanism of high-density polyethylene butt-fusion welded joint

High-density polyethylene (HDPE) pipelines are widely used for the transportation of natural gas. The butt-fusion welded joints melt and cool during the welding process, resulting in changes in mechanical properties, molecular chain spatial position microstructure, and functional groups. Herein, we investigate the aging behavior of an HDPE butt-fusion welded joint in accelerated thermal-oxidative aging tests under various temperature gradients. The Vicat softening temperature, oxidation induction time, and infrared spectrum were measured, and the microstructures were observed. The results indicated that the mechanical and chemical properties of the butt-fusion welded joint degraded with incresing aging temperature. Analysis was conducted to identify the molecular chain intersection mechanism in the heat-affected zone and the weld joining mechanism. The findings help understand the aging behavior of HDPE and provide guidelines to reduce the risk caused by butt-fusion welded joint degradation.

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来源期刊
Mechanics of Time-Dependent Materials
Mechanics of Time-Dependent Materials 工程技术-材料科学:表征与测试
CiteScore
4.90
自引率
8.00%
发文量
47
审稿时长
>12 weeks
期刊介绍: Mechanics of Time-Dependent Materials accepts contributions dealing with the time-dependent mechanical properties of solid polymers, metals, ceramics, concrete, wood, or their composites. It is recognized that certain materials can be in the melt state as function of temperature and/or pressure. Contributions concerned with fundamental issues relating to processing and melt-to-solid transition behaviour are welcome, as are contributions addressing time-dependent failure and fracture phenomena. Manuscripts addressing environmental issues will be considered if they relate to time-dependent mechanical properties. The journal promotes the transfer of knowledge between various disciplines that deal with the properties of time-dependent solid materials but approach these from different angles. Among these disciplines are: Mechanical Engineering, Aerospace Engineering, Chemical Engineering, Rheology, Materials Science, Polymer Physics, Design, and others.
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