动态跟踪土壤有机质的电化学框架

IF 10.61 Q3 Biochemistry, Genetics and Molecular Biology Biosensors and Bioelectronics: X Pub Date : 2024-01-19 DOI:10.1016/j.biosx.2024.100440
Vikram Narayanan Dhamu , Anirban Paul , Sriram Muthukumar , Shalini Prasad
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引用次数: 0

摘要

土壤健康参数是评估环境质量和了解通过碳固存减缓气候变化影响的绝佳替代指标。土壤有机质(SOM)是与土壤健康同义的参数,了解土壤有机质是通过影响土壤团聚和保水能力来建立和影响良好土壤和农艺实践的关键指标。它是土壤养分循环和吸收的重要调节器,也是全球碳循环的一个因素,因此比单纯的碳监测更具优势。虽然我们知道土壤健康状况无法直接分析,但使用一种能传递土壤物理化学和生物特征信息的高效指标是非常可取的,因为它能提供随时间变化的土壤信息分析能力,并根据地理位置建立模式。利用这一实验框架--基于氢键和 pi-pi 相互作用的 RTIL(室温离子液体)修饰电极与 OM 功能分子之间的相互作用机制,并使用电化学阻抗光谱方法进行捕捉,从而建立了首个电化学 SOM 传感器。
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Electrochemical framework for dynamic tracking of Soil Organic Matter

Soil Health parameters serve as excellent surrogate measures towards assessing environmental quality and understanding effects of climate change mitigation via carbon sequestration. Soil Organic Matter (SOM) is a parameter that is synonymous to soil health and understanding SOM is a key metric to building and influencing good soil and agronomic practices by impacting soil aggregation and water withholding capacity. It is a vital regulator of soil nutrient cycling and uptake as well as a factor in the global carbon cycle and is hence more advantageous than just carbon monitoring. While it is understood that soil health cannot be analyzed directly, the use of an efficient indicator that can relay information about the soil physico-chemical and biological characteristics is highly desirable since it offers the ability to analyze soil information over time and build patterns in terms of geographical location.

The proposed sensing system offers an in-situ electroanalytical approach to survey various electroactive substances present in the soil matrix. Utilizing this experimental framework- A mechanism of interaction between the RTIL (Room Temperature Ionic-Liquid) modified electrode and the OM functional moieties based on hydrogen bonding and pi-pi interactions captured using electrochemical impedance spectroscopy method is utilized to build a first-of-a-kind electrochemical SOM sensor.

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来源期刊
Biosensors and Bioelectronics: X
Biosensors and Bioelectronics: X Biochemistry, Genetics and Molecular Biology-Biophysics
CiteScore
4.60
自引率
0.00%
发文量
166
审稿时长
54 days
期刊介绍: Biosensors and Bioelectronics: X, an open-access companion journal of Biosensors and Bioelectronics, boasts a 2020 Impact Factor of 10.61 (Journal Citation Reports, Clarivate Analytics 2021). Offering authors the opportunity to share their innovative work freely and globally, Biosensors and Bioelectronics: X aims to be a timely and permanent source of information. The journal publishes original research papers, review articles, communications, editorial highlights, perspectives, opinions, and commentaries at the intersection of technological advancements and high-impact applications. Manuscripts submitted to Biosensors and Bioelectronics: X are assessed based on originality and innovation in technology development or applications, aligning with the journal's goal to cater to a broad audience interested in this dynamic field.
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