具有部分可渗透聚合物层的软颗粒的电泳:滑移面位置和流体动力滑移长度的影响

IF 2.2 4区 化学 Q3 CHEMISTRY, PHYSICAL Colloid and Polymer Science Pub Date : 2024-02-23 DOI:10.1007/s00396-024-05239-w
Santanu Saha, Yasuhisa Adachi, Saurabh K. Maurya, Hiroyuki Ohshima, Partha P. Gopmandal
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引用次数: 0

摘要

本文论述了核壳结构软粒子电泳的理论发展,在这种软粒子中,内部的刚性核心装饰着一层流体和离子渗透性聚合物外壳层。请注意,这种粒子类似于几种生物胶体(如细菌、病毒、腐殖酸)、功能化纳米粒子和环境实体等。对于这种结构的粒子,传统的(\zeta\)电位概念失去了意义,需要一个广泛的理论来分析粒子的电流体力学,并考虑电离液体穿过外壳层的渗透。需要注意的是,外壳层的介电常数通常低于主体水介质的介电常数,这会诱发离子分区效应。此外,在一些实际情况中,流体动力滑动可能会沿着滑动面发生。此外,由于沿内芯表面接枝了聚合物外壳层,滑动面可能并不总是位于内芯表面,因此可以假设滑动面位于表面聚合物层内的某处。滑动面将布林克曼参数不同的两个区域分开。在滑动面之外的区域,布林克曼筛选长度取有限值,这使得流体可以流过该区域。在滑动平面内的区域,布林克曼参数实际上可能等于无穷大,但电解质离子仍可穿透该区域。考虑到上述所有物理方面,我们提出了一个简单的模型来研究软颗粒在平板状态下的电泳。在弱电荷极限的基础上,我们采用 Debye-Hückel 线性化来简化控制方程,并推导出电泳迁移率的显式。根据在各种极限情况下有效的一般迁移率表达式,我们进一步推导出了几种闭式解析表达式。我们用图表说明了我们的研究结果,以突出相关参数对这种粒子的电泳迁移率的影响。此外,我们还进一步估算了粒子可能达到零迁移率的参数范围。总之,本研究提出的分析结果将有助于实验人员分析他们的发现。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Electrophoresis of soft particles with partially penetrable polymer layer: impact of location of slip plane and hydrodynamic slip length

The present article deals with the theoretical development of the electrophoresis of core-shell structured soft particles in which the inner rigid core is decorated with a fluid and ion-permeable polymeric shell layer. Note that such a particle resembles several biocolloids (e.g., bacteria, virus, humic acid), functionalized nanoparticles, and environmental entities, to name a few. For such a structured particle, the conventional \(\zeta\)-potential concept loses its meaning, and an extensive theory is required to analyze the electrohydrodynamics of the particle considering the penetration of ionized liquid across the shell layer. Note that the dielectric permittivity of the shell layer is often lower than that of the bulk aqueous medium, which induces the ion partitioning effect. Besides, in several practical situations, the hydrodynamic slipping may occur along the slipping plane. In addition, the slipping plane may not always be located along the surface of the inner core due to grafting of a polymeric shell layer along its surface, and thus, it may be assumed to be located somewhere within the surface polymeric layer. The slipping plane separates two regions with different Brinkman parameters. The region outside the slipping plane the Brinkmann screening length takes a finite value, which allows fluid flow across this region. In the region inside the slipping plane, the Brinkman parameter may practically be equal to infinity, but electrolyte ions still can penetrate this region. Considering all the physical aspects indicated above, we have proposed a simple model to study the electrophoresis of soft particles within the flat-plate regime. Based on the weak charge limit, we adopt the Debye-Hückel linearization to simplify the governing equations, and the explicit form of electrophoretic mobility is derived. Several closed-form analytic expressions are further deduced from the general mobility expressions valid under various limiting situations. We have illustrated our findings graphically to highlight the impact of pertinent parameters on the electrophoretic mobility of such a particle. In addition, we have further provided an estimate of the parametric range in which the particle may attain a zero mobility. Overall, the analytical results presented in this study will be helpful to the experimentalists to analyze their findings.

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来源期刊
Colloid and Polymer Science
Colloid and Polymer Science 化学-高分子科学
CiteScore
4.60
自引率
4.20%
发文量
111
审稿时长
2.2 months
期刊介绍: Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
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