耐热钢 HSM-7 和 HSM-10 在离子等离子氮化、低压渗碳和低压碳氮化后的耐磨性

Lidiya Kuksenova, Ravel Fahurtdinov, Maria Alekseeva
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摘要

分析了马氏体钢 HSM-7(16Cr2Ni3MoVNbNAl)和 HSM-10(13Cr3Ni3Mo2VNbNAl)的摩擦技术特性。钢材经过离子等离子氮化、低压渗碳和低压碳氮化处理。实施了两阶段淬火技术的概念:在第一阶段创建钢的热稳定细微分散状态,在第二阶段利用这种状态加速表层氮或碳的定性饱和。为了在所研究的钢材样品中形成超精细分散状态,使用了强化塑性变形(IPD)方法。该方法基于大剪切变形对微观结构的研磨。IPD 是在 700 ℃ 的温度下,在变形度为 80 % 的模具中通过温沉淀法进行的。样品的耐磨性试验是在一个特殊的台架上进行的,在塑料润滑材料的介质中,在压力为 10 兆帕和平均速度为 0.19 米/秒的条件下,在具有平面摩擦表面的配合样品上进行往复运动。结果表明,经过离子等离子氮化和真空固结后的 HSM-7 和 HSM-10 钢具有很高的耐磨性(磨损强度 I  10-10)。低压渗碳后,摩擦副样品的磨损强度值几乎相同,均为 0.3-10-10,是低压渗碳后的 3.0 倍。离子等离子氮化和低压渗碳氮化的结果是在钢表面形成了纳米结构表层,从而提高了耐磨性。本文给出了氮化钢耐磨性提高的思路。
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Wear resistance of heat-resistant steels HSM-7 and HSM-10 after ion-plasma nitriding, low-pressure carburizing and low-pressure carbonitriding
Tribotechnical characteristics of martensitic grade steels HSM-7 (16Cr2Ni3MoVNbNAl) and HSM-10 (13Cr3Ni3Mo2VNbNAl) were analyzed. Steels underwent ion plasma nitriding, low-pressure carburizing and low-pressure carbonitriding. The concept of a two-stage hardening technology has been implemented: the creation of a thermally stable finely dispersed state of steel at the first stage and the use of such a state for accelerated and qualitative saturation of the surface layer with nitrogen or carbon at the second stage. To create an ultra-finely divided state in the samples of steels under investigation, the method of intensive plastic deformation (IPD) was used. The method is based on the grinding of the microstructure due to large shear deformations. IPD was performed by the method of warm precipitation in a die with a degree of deformation of 80 % at a temperature of 700 ℃. The wear resistance tests of the samples were carried out on a special stand with reciprocating motion in the medium of a plastic lubricant material of mating samples having flat friction surfaces at a pressure of 10 MPa and an average velocity of 0,19 m/s. It is shown that HSM-7 and HSM-10 steels after ion-plasma nitriding and vacuum cementation have high wear resistance (wear intensity I  10-10). After low-pressure carbonitriding, the values of the wear intensity of the friction pair samples are almost the same and amount to 0,3·10-10, which is ~3,0 times less than after low-pressure carburizing. As a result of ion-plasma nitriding and low-pressure carbonitriding, a nanostructured surface layer is formed on steel surfaces contributing to wear resistance increase. The ideas concerning nitrided steel score resistance increase are given.
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