等离子电解氧化法处理的 AH36 钢和 TC4 合金的电化学腐蚀行为研究

IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Engineering and Performance Pub Date : 2024-05-09 DOI:10.1007/s11665-024-09535-y
Xin Li, Qiaoqin Guo, Huishan Jin, Mingxu Li, Zhong Yang, Yajian Wang
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引用次数: 0

摘要

采用等离子体电解氧化(PEO)技术在钛合金表面制备陶瓷涂层,以防止 AH36/TC4(PEO)的电化学腐蚀。结果表明,经过 PEO 处理后,基体表面形成了具有微孔的陶瓷涂层。电压较低时,孔隙较小。随着电压的升高,涂层的厚度和孔径都有所增加。经过 PEO 处理后,平均电化学腐蚀率降低了 60%,电化学对中 AH36 表面的点蚀坑数量也减少了。与 TC4(PEO)结合的 AH36 的拉伸强度和伸长率分别降低了 4.0% 和 11.9%。腐蚀产物 Fe2O3-H2O 和 FeO(OH) 的含量降低,拉伸试样的腐蚀面积明显缩小。因此,PEO 工艺能有效降低 AH36/TC4(PEO)的电化学腐蚀敏感性,减轻阳极 AH36 的延展性和韧性降低程度,提高耐腐蚀性能。
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Study on Galvanic Corrosion Behavior of AH36 Steel and TC4 Alloy Processed by Plasma Electrolytic Oxidation

The plasma electrolytic oxidation (PEO) technology was used to prepare ceramic coating on the surface of titanium alloy to prevent the galvanic corrosion of AH36/TC4(PEO). The results showed that after PEO treatment, ceramic coating with micropores was formed on the substrate surface. When the voltage was low, the pore size was small. With the increase of voltage, the thickness and the pore sizes of the coating increased. After PEO process, the average galvanic corrosion rate was reduced by 60%, and the number of pitting pits on the AH36 surface in the galvanic pair was reduced. The tensile strength and elongation of AH36 coupled with TC4(PEO) decreased by 4.0% and 11.9%, respectively. The contents of the corrosion products Fe2O3·H2O and FeO(OH) decreased, and the corrosion area of the tensile specimen was evidently reduced. Therefore, the PEO process can effectively reduce the galvanic corrosion susceptibility of AH36/TC4(PEO), alleviate the reduction degree of ductility and toughness of anode AH36, and enhance the corrosion resistance performance.

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来源期刊
Journal of Materials Engineering and Performance
Journal of Materials Engineering and Performance 工程技术-材料科学:综合
CiteScore
3.90
自引率
13.00%
发文量
1120
审稿时长
4.9 months
期刊介绍: ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance. The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication. Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered
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