Carolina Mejía Salazar, Julián Acevedo, Jennifer Laverde, Diana López
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However, there are not enough studies to help understand how the type of nitrogen precursor influences the development of specific nitrogen functionalities to favor the retention of lithium polysulfide species. This work seeks to determine the effect of the use of different nitrogen precursors on the structural changes of the mesoporous carbon materials prepared, and thus evaluate the electrochemical behavior of Li–S cells correlating the type of nitrogen functionality generated when the precursor is variated with the charge/discharge capacity developed during the cell operation. For this study, different carbon materials were prepared by the variation of the nitrogen source (melamine, ethylenediamine, and hexadecylamine) to obtain a N-doped mesoporous carbon with different distributions of nitrogen functionalities in its structure. The use of the primary amine ethylenediamine as a nitrogen precursor in the formation of structured carbon materials favored elemental sulfur infiltration into its pores, resulting in the maximum sulfur content within the pores and interacting with the carbonaceous matrix (78.8 wt.%). The carbon material prepared with this precursor resulted in a higher content of N-pyridinic functionality, which, combined with the high content of N-pyrrolic, resulted in the highest specific discharge capacity at 0.1 C after 100 cycles when compared to cells assembled with materials derived from the use of melamine and hexadecylamine precursors. The cell assembled with the electrode formed from ethylenediamine as a nitrogen precursor presented an initial discharge capacity of 918 mA h g−1 with a Coulombic efficiency of ~83.4% at 0.1 C after 100 cycles.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of the Nitrogen Precursor in the Development of N-Functionalities in a Mesoporous Carbon Material and Its Effect on the Li–S Cells’ Electrochemistry\",\"authors\":\"Carolina Mejía Salazar, Julián Acevedo, Jennifer Laverde, Diana López\",\"doi\":\"10.3390/batteries10060169\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Li–S batteries are positioned as a strong alternative for efficient energy storage due to their high theoretical energy density and their theoretical specific capacity (1675 mA h g−1) compared to current Li-ion batteries; however, their commercialization is affected by the rapid decay of the specific capacity as a consequence of the different species of lithium polysulfides that are generated during the charge–discharge processes. The use of nitrogen-doped mesoporous carbon materials has been shown to have the ability to confer electronic conductivity to sulfur and retain the lithium polysulfide species. However, there are not enough studies to help understand how the type of nitrogen precursor influences the development of specific nitrogen functionalities to favor the retention of lithium polysulfide species. This work seeks to determine the effect of the use of different nitrogen precursors on the structural changes of the mesoporous carbon materials prepared, and thus evaluate the electrochemical behavior of Li–S cells correlating the type of nitrogen functionality generated when the precursor is variated with the charge/discharge capacity developed during the cell operation. 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引用次数: 0
摘要
与目前的锂离子电池相比,锂-S 电池具有理论能量密度高、理论比容量大(1675 mA h g-1)的特点,因此被定位为高效储能的有力替代品;然而,由于在充放电过程中会产生不同种类的多硫化锂,比容量会迅速衰减,这影响了锂-S 电池的商业化。研究表明,使用掺氮介孔碳材料能够赋予硫以电子导电性,并保留多硫化锂物种。然而,目前还没有足够的研究来帮助了解氮前驱体的类型如何影响特定氮功能的发展,从而有利于保留多硫化锂。本研究旨在确定使用不同的氮前驱体对所制备介孔碳材料结构变化的影响,从而评估锂-S 电池的电化学行为,将前驱体变化时产生的氮功能类型与电池运行过程中形成的充放电容量联系起来。在这项研究中,通过改变氮源(三聚氰胺、乙二胺和十六胺)制备了不同的碳材料,从而获得了氮掺杂介孔碳,其结构中的氮官能团分布各不相同。在形成结构碳材料的过程中,使用伯胺乙二胺作为氮前体有利于硫元素渗入其孔隙,从而使孔隙中的硫含量达到最高,并与碳质基体相互作用(78.8 wt.%)。与使用三聚氰胺和十六胺前体制备的材料组装的电池相比,使用这种前体制备的碳材料具有更高的 N-吡啶官能团含量,再加上高含量的 N-吡咯烷酮,因此在 0.1 C 条件下循环 100 次后的比放电容量最高。用乙二胺作为氮前驱体形成的电极组装的电池在 100 次循环后,在 0.1 C 下的初始放电容量为 918 mA h g-1,库仑效率约为 83.4%。
Influence of the Nitrogen Precursor in the Development of N-Functionalities in a Mesoporous Carbon Material and Its Effect on the Li–S Cells’ Electrochemistry
Li–S batteries are positioned as a strong alternative for efficient energy storage due to their high theoretical energy density and their theoretical specific capacity (1675 mA h g−1) compared to current Li-ion batteries; however, their commercialization is affected by the rapid decay of the specific capacity as a consequence of the different species of lithium polysulfides that are generated during the charge–discharge processes. The use of nitrogen-doped mesoporous carbon materials has been shown to have the ability to confer electronic conductivity to sulfur and retain the lithium polysulfide species. However, there are not enough studies to help understand how the type of nitrogen precursor influences the development of specific nitrogen functionalities to favor the retention of lithium polysulfide species. This work seeks to determine the effect of the use of different nitrogen precursors on the structural changes of the mesoporous carbon materials prepared, and thus evaluate the electrochemical behavior of Li–S cells correlating the type of nitrogen functionality generated when the precursor is variated with the charge/discharge capacity developed during the cell operation. For this study, different carbon materials were prepared by the variation of the nitrogen source (melamine, ethylenediamine, and hexadecylamine) to obtain a N-doped mesoporous carbon with different distributions of nitrogen functionalities in its structure. The use of the primary amine ethylenediamine as a nitrogen precursor in the formation of structured carbon materials favored elemental sulfur infiltration into its pores, resulting in the maximum sulfur content within the pores and interacting with the carbonaceous matrix (78.8 wt.%). The carbon material prepared with this precursor resulted in a higher content of N-pyridinic functionality, which, combined with the high content of N-pyrrolic, resulted in the highest specific discharge capacity at 0.1 C after 100 cycles when compared to cells assembled with materials derived from the use of melamine and hexadecylamine precursors. The cell assembled with the electrode formed from ethylenediamine as a nitrogen precursor presented an initial discharge capacity of 918 mA h g−1 with a Coulombic efficiency of ~83.4% at 0.1 C after 100 cycles.