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Copper Wire Resistance Corrosion Test for Assessing Copper Compatibility of E-Thermal Fluids for Battery Electric Vehicles (BEVs) 用于评估电池电动汽车 (BEV) 电子导热液体铜兼容性的铜线电阻腐蚀测试
IF 4.6 4区 化学 Q2 ELECTROCHEMISTRY Pub Date : 2024-08-09 DOI: 10.3390/batteries10080285
Bernardo Tormos, Santiago Ruiz, Jorge Alvis-Sanchez, L. I. Farfán-Cabrera
This study aims to assess the compatibility of various e-thermal fluids for immersion cooling in battery electric vehicles through a copper wire resistance corrosion test. The tested fluids include a polyalphaolefin, diester, mineral oil API G-III, transformer oil, and a fully formulated dielectric coolant. The test was conducted at 130 °C for 336 h, and the resistance of the copper wires was monitored in vapor and oil phases. By comparing the resistance variation and analyzing portions of the wires through scanning electron microscopy, it was found that the vapor phase of PAO and diester in one of the tests exhibited significant corrosion, while the dielectric coolant showed minimal corrosive effects, implying better compatibility. These results provide insights into the corrosion behavior and compatibility of the fluids with copper, which are essential for selecting suitable dielectric fluids for immersion cooling applications in electric vehicles.
本研究旨在通过铜线电阻腐蚀测试,评估电池电动汽车浸入式冷却所使用的各种电热冷却液的兼容性。测试的液体包括聚α烯烃、二元醇、矿物油 API G-III、变压器油和全配方电介质冷却液。试验在 130 °C 的温度下进行了 336 小时,监测了铜线在气相和油相的电阻。通过比较电阻变化和用扫描电子显微镜分析铜丝的部分,发现其中一项测试中 PAO 和二元醇的气相表现出明显的腐蚀性,而电介质冷却剂的腐蚀性极小,这意味着两者具有更好的兼容性。这些结果有助于深入了解液体的腐蚀行为和与铜的兼容性,这对于为电动汽车的浸入式冷却应用选择合适的介电液体至关重要。
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引用次数: 0
Advancements and Challenges in Perovskite-Based Photo-Induced Rechargeable Batteries and Supercapacitors: A Comparative Review 基于包晶石的光诱导充电电池和超级电容器的进展与挑战:比较综述
IF 4.6 4区 化学 Q2 ELECTROCHEMISTRY Pub Date : 2024-08-08 DOI: 10.3390/batteries10080284
Anil Kumar M. R., Atiyeh Nekahi, Mohamed Djihad Bouguern, Dongling Ma, Karim Zaghib
Perovskite-based photo-batteries (PBs) have been developed as a promising combination of photovoltaic and electrochemical technology due to their cost-effective design and significant increase in solar-to-electric power conversion efficiency. The use of complex metal oxides of the perovskite-type in batteries and photovoltaic cells has attracted considerable attention. Because of its variable bandgap, non-rigid structure, high light absorption capacity, long charge carrier diffusion length, and high charge mobility, this material has shown promise in energy storage devices, especially Li-ion batteries (LIBs) and PBs. This review paper focuses on recent progress and comparative analysis of PBs using perovskite-based materials. The practical application of these batteries as dependable power sources faces significant technical and financial challenges because solar radiation is alternating. In order to address this, research is being performed on PBs with the integration of perovskite solar cells (PSCs) as a way to balance energy availability and demand, cut down on energy waste, and stabilize power output for wearable and portable electronics as well as energy storage applications.
基于透辉石的光电池(PBs)是光伏技术和电化学技术的一种很有前途的组合,因为其设计成本低,而且能显著提高太阳能到电能的转换效率。在电池和光伏电池中使用复杂的透辉石型金属氧化物引起了广泛关注。这种材料具有可变带隙、非刚性结构、高光吸收能力、长电荷载流子扩散长度和高电荷迁移率等特点,因此在储能设备,尤其是锂离子电池(LIB)和光伏电池中大有可为。本综述论文重点介绍了使用透辉石基材料的 PB 的最新进展和比较分析。由于太阳辐射是交替变化的,因此将这些电池作为可靠电源的实际应用面临着巨大的技术和经济挑战。为了解决这个问题,目前正在对集成了透辉石太阳能电池 (PSC) 的 PB 进行研究,以此来平衡能源供应和需求,减少能源浪费,并稳定可穿戴和便携式电子设备以及储能应用的电力输出。
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引用次数: 0
A Physics–Guided Machine Learning Approach for Capacity Fading Mechanism Detection and Fading Rate Prediction Using Early Cycle Data 利用早期周期数据进行容量衰减机制检测和衰减率预测的物理引导机器学习方法
IF 4.6 4区 化学 Q2 ELECTROCHEMISTRY Pub Date : 2024-08-08 DOI: 10.3390/batteries10080283
Jiwei Yao, Qiang Gao, Tao Gao, Benben Jiang, Kody M. Powell
Lithium–ion battery development necessitates predicting capacity fading using early cycle data to minimize testing time and costs. This study introduces a hybrid physics–guided data–driven approach to address this challenge by accurately determining the dominant fading mechanism and predicting the average capacity fading rate. Physics–guided features, derived from the electrochemical properties and behaviors within the battery, are extracted from the first five cycles to provide meaningful, interpretable, and predictive data. Unlike previous models that rely on a single regression approach, our method utilizes two separate regression models tailored to the identified dominant fading mechanisms. Our model achieves 95.6% accuracy in determining the dominant fading mechanism using data from the second cycle and a mean absolute percentage error of 17.09% in predicting lifetime capacity fade from the first five cycles. This represents a substantial improvement over state–of–the–art models, which have an error rate approximately three times higher. This study underscores the significance of physics–guided data characterization and the necessity of identifying the primary fading mechanism prior to predicting the capacity fading rate in lithium–ion batteries.
锂离子电池的开发需要利用早期循环数据预测容量衰减,以最大限度地减少测试时间和成本。本研究介绍了一种混合物理引导数据驱动方法,通过准确确定主要衰减机制和预测平均容量衰减率来应对这一挑战。从电池内部的电化学特性和行为中提取的物理导向特征,可提供有意义、可解释和可预测的数据。与以往依赖单一回归方法的模型不同,我们的方法采用了两个独立的回归模型,专门针对已确定的主要衰减机制。我们的模型利用第二个周期的数据确定主要衰减机制的准确率达到 95.6%,预测前五个周期的寿命容量衰减的平均绝对百分比误差为 17.09%。与误差率高出约三倍的最先进模型相比,这是一项重大改进。这项研究强调了物理引导数据特征描述的重要性,以及在预测锂离子电池容量衰减率之前确定主要衰减机制的必要性。
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引用次数: 0
A Novel Reaction Rate Parametrization Method for Lithium-Ion Battery Electrochemical Modelling 用于锂离子电池电化学建模的新型反应速率参数化方法
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-14 DOI: 10.3390/batteries10060205
Alain Goussian, Loïc Assaud, Issam Baghdadi, Cédric Nouillant, Sylvain Franger
To meet the ever-growing worldwide electric vehicle demand, the development of advanced generations of lithium-ion batteries is required. To this end, modelling is one of the pillars for the innovation process. However, modelling batteries containing a large number of different mechanisms occurring at different scales remains a field of research that does not provide consensus for each particular model or approach. Parametrization as part of the modelling process appears to be one of the issues when it comes to building a high-fidelity model of a target cell. In this paper, a particular parameter identification is therefore discussed. Indeed, even if Butler–Volmer is a well-known equation in the electrochemistry field, identification of its reaction rate constant or exchange current density parameters is lacking in the literature. Thus, we discuss the process described in the literature and propose a new protocol that expects to overcome certain difficulties whereas the hypothesis of calculation and measurement maintains high sensitivity.
为满足全球日益增长的电动汽车需求,需要开发先进的锂离子电池。为此,建模是创新过程的支柱之一。然而,电池建模包含在不同尺度上发生的大量不同机制,这仍然是一个研究领域,并没有为每个特定模型或方法提供共识。作为建模过程的一部分,参数化似乎是建立目标电池高保真模型的问题之一。因此,本文将讨论一种特定的参数识别方法。事实上,即使 Butler-Volmer 是电化学领域的著名方程,文献中也缺乏对其反应速率常数或交换电流密度参数的识别。因此,我们讨论了文献中描述的过程,并提出了一种新的方案,希望能克服某些困难,同时在计算和测量假设中保持高灵敏度。
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引用次数: 0
A Deep Learning Approach for Online State of Health Estimation of Lithium-Ion Batteries Using Partial Constant Current Charging Curves 利用部分恒流充电曲线在线估计锂离子电池健康状况的深度学习方法
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-14 DOI: 10.3390/batteries10060206
Mano Schmitz, Julia Kowal
The accurate state of health (SOH) estimation of lithium-ion batteries (LIBs) during operation is crucial to ensure optimal performance, prolonging battery life and preventing unexpected failure or safety hazards. This work presents a storage- and performance-optimised deep learning approach to estimate the capacity-based SOH of LIBs using raw sensor data from partial charging curves under constant current condition. The proposed model is based on a combination of a one-dimensional convolutional and long short-term memory neural network, and processes time, voltage, and incremental capacity of partial charging curves as time series. The model is cross-validated on different ageing scenarios, reaching an overall MAE = 0.418% and RMSE = 0.531%, promising an accurate SOH estimation of LIBs under varying usage and environmental conditions in a real-world application.
准确估计锂离子电池(LIB)在运行期间的健康状况(SOH)对于确保最佳性能、延长电池寿命、防止意外故障或安全隐患至关重要。本研究提出了一种存储和性能优化的深度学习方法,利用恒定电流条件下部分充电曲线的原始传感器数据来估计锂离子电池基于容量的 SOH。所提出的模型基于一维卷积神经网络和长短期记忆神经网络的组合,将部分充电曲线的时间、电压和增量容量作为时间序列进行处理。该模型在不同的老化情况下进行了交叉验证,总体 MAE = 0.418%,RMSE = 0.531%,有望在实际应用中准确估计锂电池在不同使用和环境条件下的 SOH。
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引用次数: 0
Low-Temperature-Tolerant Aqueous Proton Battery with Porous Ti3C2Tx MXene Electrode and Phosphoric Acid Electrolyte 采用多孔 Ti3C2Tx MXene 电极和磷酸电解液的耐低温水性质子电池
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-14 DOI: 10.3390/batteries10060207
Jun Zhu, Xude Li, Bingqing Hu, Shanhai Ge, Jiang Xu
Supercapacitors have long suffered from low energy density. Here, we present a high-energy, high-safety, and temperature-adaptable aqueous proton battery utilizing two-dimensional Ti3C2Tx MXenes as anode materials. Additionally, our work aims to provide further insights into the energy storage mechanism of Ti3C2Tx in acid electrolytes. Our findings reveal that the ion transport mechanism of Ti3C2Tx remains consistent in both H2SO4 and H3PO4 electrolytes. The mode of charge transfer depends on its terminal groups. Specifically, the hydrogen bonding network formed by water molecules adsorbed by hydroxyl functional groups under van der Waals forces enables charge transfer in the form of naked H+ through the Grotthuss mechanism. In contrast, the hydrophobic channel formed by oxygen and halogen terminal groups facilitates rapid charge transfers in the form of hydronium ion via the vehicle mechanism, owing to negligible interfacial effect. Herein, we propose an aqueous proton battery based on porous hydroxy-poor Ti3C2Tx MXene anode and pre-protonated CuII[FeIII(CN)6]2/3∙4H2O (H-TBA) cathode in a 9.5 M H3PO4 solution. This proton battery operates through hydrated H+/H+ transfer, leading to good electrochemical performance, as evidenced by 26 Wh kg−1 energy density and 162 kW kg−1 power density at room temperature and an energy density of 17 Wh kg−1 and a power density of 7.4 kW kg−1 even at −60 °C.
长期以来,超级电容器一直存在能量密度低的问题。在这里,我们利用二维 Ti3C2Tx MXenes 作为阳极材料,提出了一种高能量、高安全性和温度适应性强的水性质子电池。此外,我们的研究还旨在进一步深入了解 Ti3C2Tx 在酸性电解质中的储能机制。我们的研究结果表明,Ti3C2Tx 在 H2SO4 和 H3PO4 电解质中的离子传输机制保持一致。电荷转移模式取决于其末端基团。具体来说,羟基官能团吸附的水分子在范德华力作用下形成的氢键网络可通过 Grotthuss 机制实现裸 H+ 形式的电荷转移。与此相反,氧和卤素末端基团形成的疏水通道由于可忽略的界面效应,可通过载体机制促进氢离子形式的电荷快速转移。在此,我们提出了一种水性质子电池,它基于多孔疏水性 Ti3C2Tx MXene 阳极和 9.5 M H3PO4 溶液中的预质子化 CuII[FeIII(CN)6]2/3∙4H2O (H-TBA)阴极。这种质子电池通过水合 H+/H+ 转移进行工作,具有良好的电化学性能,室温下的能量密度为 26 Wh kg-1,功率密度为 162 kW kg-1,即使在零下 60 °C,能量密度也达到 17 Wh kg-1,功率密度为 7.4 kW kg-1。
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引用次数: 0
Correction: Mirandona-Olaeta et al. Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries. Batteries 2023, 9, 588 更正:Mirandona-Olaeta et al. Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries.电池 2023,9,588
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-13 DOI: 10.3390/batteries10060203
Alexander Mirandona-Olaeta, E. Goikolea, Senen Lanceros-Mendez, A. Fidalgo-Marijuan, Idoia Ruiz de Larramendi
The authors wish to make the following corrections to their paper [...]
作者希望对其论文做如下更正[......]
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引用次数: 0
Recent Progress of Deep Learning Methods for Health Monitoring of Lithium-Ion Batteries 深度学习方法在锂离子电池健康监测方面的最新进展
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-13 DOI: 10.3390/batteries10060204
S. S. Madani, C. Ziebert, P. Vahdatkhah, S. Sadrnezhaad
In recent years, the rapid evolution of transportation electrification has been propelled by the widespread adoption of lithium-ion batteries (LIBs) as the primary energy storage solution. The critical need to ensure the safe and efficient operation of these LIBs has positioned battery management systems (BMS) as pivotal components in this landscape. Among the various BMS functions, state and temperature monitoring emerge as paramount for intelligent LIB management. This review focuses on two key aspects of LIB health management: the accurate prediction of the state of health (SOH) and the estimation of remaining useful life (RUL). Achieving precise SOH predictions not only extends the lifespan of LIBs but also offers invaluable insights for optimizing battery usage. Additionally, accurate RUL estimation is essential for efficient battery management and state estimation, especially as the demand for electric vehicles continues to surge. The review highlights the significance of machine learning (ML) techniques in enhancing LIB state predictions while simultaneously reducing computational complexity. By delving into the current state of research in this field, the review aims to elucidate promising future avenues for leveraging ML in the context of LIBs. Notably, it underscores the increasing necessity for advanced RUL prediction techniques and their role in addressing the challenges associated with the burgeoning demand for electric vehicles. This comprehensive review identifies existing challenges and proposes a structured framework to overcome these obstacles, emphasizing the development of machine-learning applications tailored specifically for rechargeable LIBs. The integration of artificial intelligence (AI) technologies in this endeavor is pivotal, as researchers aspire to expedite advancements in battery performance and overcome present limitations associated with LIBs. In adopting a symmetrical approach, ML harmonizes with battery management, contributing significantly to the sustainable progress of transportation electrification. This study provides a concise overview of the literature, offering insights into the current state, future prospects, and challenges in utilizing ML techniques for lithium-ion battery health monitoring.
近年来,锂离子电池(LIB)作为主要的储能解决方案被广泛采用,推动了交通电气化的快速发展。确保这些锂离子电池安全高效运行的迫切需求使电池管理系统(BMS)成为这一领域的关键组件。在 BMS 的各种功能中,状态和温度监测对于智能 LIB 管理至关重要。本综述将重点关注电池组健康管理的两个关键方面:健康状态(SOH)的准确预测和剩余使用寿命(RUL)的估算。实现精确的 SOH 预测不仅能延长电池组寿命,还能为优化电池使用提供宝贵的见解。此外,准确的 RUL 估计对于高效的电池管理和状态估计至关重要,尤其是在电动汽车需求持续激增的情况下。本综述强调了机器学习(ML)技术在提高 LIB 状态预测能力的同时降低计算复杂性的重要意义。通过深入探讨该领域的研究现状,综述旨在阐明在 LIB 中利用 ML 的前景广阔的未来途径。值得注意的是,综述强调了先进的 RUL 预测技术日益增长的必要性,以及这些技术在应对电动汽车需求激增所带来的挑战方面的作用。本综述指出了现有的挑战,并提出了克服这些障碍的结构化框架,强调开发专门针对可充电锂电池的机器学习应用。将人工智能(AI)技术整合到这项工作中至关重要,因为研究人员希望加快电池性能的进步,并克服目前与锂电池相关的局限性。通过采用对称的方法,人工智能与电池管理相协调,极大地促进了交通电气化的可持续发展。本研究简明扼要地概述了相关文献,深入探讨了利用 ML 技术进行锂离子电池健康监测的现状、未来前景和挑战。
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引用次数: 0
Investigations into the Charge Times of Lead–Acid Cells under Different Partial-State-of-Charge Regimes 不同部分充电状态下铅酸电池充电时间的研究
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-11 DOI: 10.3390/batteries10060201
Max Parker, Richard McMahon
Partial state of charge (PSOC) is an important use case for lead–acid batteries. Charging times in lead–acid cells and batteries can be variable, and when used in PSOC operation, the manufacturer’s recommended charge times for single-cycle use are not necessarily applicable. Knowing how long charging will take and what the variability in time required is allows for better planning of operations and algorithm creation for battery energy storage system (BESS) manufacturers. This paper details and demonstrates a procedure for identifying the charging time of cells when different charge throughputs occur prior to reaching full charge. The results showed that the charging time in PSOC operations was highly variable when a charge-factor-controlled full-charge procedure was used. Also noted were that higher voltages for the same state of charge were reached as the number of cycles following reaching full charge increased. None of the regimes tested in this paper caused any significant capacity degradation, which demonstrates that PSOC operations can be performed even on cells not specifically designed for them, provided the correct regime is chosen.
部分充电状态(PSOC)是铅酸蓄电池的一个重要用例。铅酸电池和蓄电池的充电时间是可变的,在 PSOC 操作中使用时,制造商推荐的单次循环充电时间并不一定适用。了解充电需要多长时间以及所需时间的可变性,有助于更好地规划操作,并为电池储能系统(BESS)制造商创建算法。本文详细介绍并演示了一种程序,用于确定在达到完全充电之前出现不同充电吞吐量时的电池充电时间。结果表明,当使用充电因子控制的满充程序时,PSOC 操作中的充电时间变化很大。此外,随着达到完全充电后循环次数的增加,相同充电状态下的电压也会升高。本文测试的所有机制都不会造成明显的容量下降,这表明只要选择正确的机制,即使不是专门为 PSOC 操作而设计的电池也能进行 PSOC 操作。
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引用次数: 0
Design Principles and Development Status of Flexible Integrated Thin and Lightweight Zinc-Ion Batteries 柔性集成轻薄型锌- 离子电池的设计原理和开发现状
IF 4 4区 化学 Q2 Engineering Pub Date : 2024-06-10 DOI: 10.3390/batteries10060200
Xuxian Liu, Yongchang Jiang, Yaqun Wang, Lijia Pan
The rapid advancement of wearable devices and flexible electronics has spurred an increasing need for high-performance, thin, lightweight, and flexible energy storage devices. In particular, thin and lightweight zinc-ion batteries require battery materials that possess exceptional flexibility and mechanical stability to accommodate complex deformations often encountered in flexible device applications. Moreover, the development of compact and thin battery structures is essential to minimize the overall size and weight while maintaining excellent electrochemical performance, including high energy density, long cycle life, and stable charge/discharge characteristics, to ensure their versatility across various applications. Researchers have made significant strides in enhancing the battery’s performance by optimizing crucial components such as electrode materials, electrolytes, separators, and battery structure. This review provides a comprehensive analysis of the design principles essential for achieving thinness in zinc-ion batteries, along with a summary of the preparation methods and potential applications of these batteries. Moreover, it delves into the challenges associated with achieving thinness in zinc-ion batteries and proposes effective countermeasures to address these hurdles. This review concludes by offering insights into future developments in this field, underscoring the continual advancements and innovations that can be expected.
随着可穿戴设备和柔性电子产品的快速发展,人们对高性能、轻薄、柔性储能设备的需求与日俱增。特别是轻薄型锌离子电池,需要电池材料具有优异的柔韧性和机械稳定性,以适应柔性设备应用中经常遇到的复杂变形。此外,开发紧凑、轻薄的电池结构对于最大限度地减小整体尺寸和重量,同时保持优异的电化学性能(包括高能量密度、长循环寿命和稳定的充放电特性)以确保其在各种应用中的通用性至关重要。研究人员通过优化电极材料、电解质、隔膜和电池结构等关键部件,在提高电池性能方面取得了重大进展。本综述全面分析了实现锌离子电池薄型化的基本设计原则,并总结了这些电池的制备方法和潜在应用。此外,它还深入探讨了实现锌离子电池薄型化的相关挑战,并提出了解决这些障碍的有效对策。本综述最后对这一领域的未来发展提出了见解,强调了可以预期的持续进步和创新。
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引用次数: 0
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