噻芴酮与 9,10-二甲基蒽的 Diels-Alder 反应动力学

IF 0.8 4区化学 Q4 CHEMISTRY, ORGANIC Russian Journal of Organic Chemistry Pub Date : 2024-06-24 DOI:10.1134/S1070428024040055

D. A. Kornilov, A. G. Mustafin

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引用次数: 0

摘要

摘要测定了硫代芴酮和 9,10-二甲基蒽在甲苯中发生 Diels-Alder 反应的速率常数（温度范围为 15 至 35°C），并计算了活化焓和活化熵。通过核磁共振光谱法、质谱法和元素分析法确定了所得加合物的结构。

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Kinetics of the Diels–Alder Reaction of Thiofluorenone with 9,10-Dimethylanthracene

Rate constants of the Diels–Alder reaction of thiofluorenone and 9,10-dimethylanthracene in toluene have been determined in the temperature range of 15 to 35°C, and the enthalpy and entropy of activation have been calculated. The structure of the resulting adduct was determined by NMR spectroscopy, mass spectrometry, and elemental analysis.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.