三聚氰胺-甲醛纳米复合微球上刚果红的合成、表征和吸附研究

IF 2.2 4区 化学 Q3 CHEMISTRY, PHYSICAL Colloid and Polymer Science Pub Date : 2024-08-02 DOI:10.1007/s00396-024-05303-5
Massoumeh Bagheri, Mina Mohammadi, Fahimeh Farshi Azhar
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引用次数: 0

摘要

考虑到偶氮阴离子染料对环境和人类健康的致癌和致突变特性,开发去除这些水污染物的高效吸附剂非常重要。因此,本研究的主要目的是开发具有成本效益的高效三聚氰胺-甲醛(MF)微球,用于去除废水中的阴离子染料。通过简单的缩聚方法,使用不同量的掺杂石墨烯量子点(NGQDs)制备了三聚氰胺-甲醛纳米复合微球(MF-NGQD)。根据扫描电镜图像,MF-NGQD 微球的单分散度高达 10 wt%,平均直径为 427 nm,小于 MF 微球的⁓2.1 μm。zeta电位(ZP)随溶液pH值变化的测量结果表明,ZP量不仅受溶液pH值的显著影响,还受微球中NGQDs含量的影响。BET 结果显示,与 MF 微球(5.40 cm3 g-1 和 0.017 cm3 g-1)相比,纳米复合微球的表面积更大,孔隙率更高(11.40 m2 g-1 和 0.030 cm3 g-1)。为了研究微球对刚果红(CR)的吸附特性,进行了批量吸附实验。结果表明,在 pH 值为 6.0、C0 为 50 mg L-1 的条件下,0.05 g/25 mL 的 MF-NGQD 微球能在 45 分钟内去除高达 97% 的刚果红,吸附容量为 91.74 mg g-1。通过等温线和动力学研究对吸附过程进行了进一步分析,结果表明分别与 Freundlich 模型和伪二阶模型有较好的拟合。总之,我们的研究结果表明,MF-NGQD-10 微球是去除纺织废水中刚果红等阴离子染料的高效吸附剂,为废水处理提供了一种前景广阔的解决方案。未来的研究应探索这些微球的可扩展性和实际应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Synthesis, characterization, and adsorption study of Congo Red on melamine-formaldehyde nanocomposite microspheres

Considering the carcinogenic and mutagenic properties of azo anionic dyes on the environment and human health, the development of efficient adsorbents for the removal of these water pollutants is very important. Therefore, the main aim of this research is to develop cost-effective and efficient melamine-formaldehyde (MF) microspheres for the removal of anionic dyes from wastewater. MF nanocomposite (MF-NGQD) microspheres were prepared using varying amounts of N-doped graphene quantum dots (NGQDs) through a simple polycondensation method. According to the SEM images, the MF-NGQD microspheres contain up to 10 wt% monodisperse, with an average diameter of 427 nm, which is smaller than the MF microspheres with a diameter of ⁓2.1 μm. The measurement of zeta potential (ZP) as a function of solution pH showed that the amount of ZP is significantly affected not only by the pH of the solution but also by the content of NGQDs in the microspheres. BET results revealed higher surface area and larger pore volume of nanocomposite microspheres (11.40 m2 g−1 and 0.030 cm3 g−1) compared to MF microspheres (5.40 cm3 g−1 and 0.017 cm3 g−1). Batch adsorption experiments were carried out to investigate the adsorption properties of microspheres on Congo Red (CR). The results indicated that MF-NGQD microspheres with an amount of 0.05 g/25 mL were able to remove CR up to 97% at pH 6.0 with C0 of 50 mg L−1 in 45 min with an adsorption capacity of 91.74 mg g−1. Adsorption processes were further analyzed through isotherm and kinetic studies, which showed a better fit with the Freundlich model and pseudo-second-order model, respectively. In conclusion, our finding demonstrates that MF-NGQD-10 microspheres are highly effective adsorbents for the removal of anionic dyes such as Congo Red from textile effluents, offering a promising solution for wastewater treatment. Future studies should explore the scalability and real-world application of these microspheres.

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来源期刊
Colloid and Polymer Science
Colloid and Polymer Science 化学-高分子科学
CiteScore
4.60
自引率
4.20%
发文量
111
审稿时长
2.2 months
期刊介绍: Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
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