臭氧-芬顿耦合强化法处理糠醛废水的实验研究

IF 3.8 3区 工程技术 Q3 ENERGY & FUELS Chemical Engineering and Processing - Process Intensification Pub Date : 2024-08-26 DOI:10.1016/j.cep.2024.109960
Keyan Liu, Leiming Wang, Yifeng Han, Jinliang Tao, Feng Wei
{"title":"臭氧-芬顿耦合强化法处理糠醛废水的实验研究","authors":"Keyan Liu,&nbsp;Leiming Wang,&nbsp;Yifeng Han,&nbsp;Jinliang Tao,&nbsp;Feng Wei","doi":"10.1016/j.cep.2024.109960","DOIUrl":null,"url":null,"abstract":"<div><p>Furfural production generates wastewater characterized by high concentration, strong acidity, and poor biodegradability, necessitating treatment before discharge. The Fenton process, known for its cost-effectiveness, is widely used for industrial wastewater treatment. However, it has limitations such as a narrow pH operating range and significant secondary pollution. To optimize this, researchers have explored combining Fenton with other processes, yet few have studied its synergy with O<sub>3</sub>. This study investigates the advantages of O<sub>3</sub>/Fenton coupling in treating furfural wastewater, comparing the capabilities of O<sub>3</sub>, O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub>, Fenton, and O<sub>3</sub>/Fenton processes. Results show that ozone-Fenton coupling exhibits superior industrial treatment performance. Post-treatment, the wastewater's B/C ratio reached 0.43, TOC removal rate was 33.6%, and ozone utilization efficiency was 74.6%, surpassing other methods. UV absorption spectra analysis indicated enhanced degradation of aromatic compounds, transforming them into smaller organic molecules. This study highlights ozone-Fenton coupling as a low-cost, effective enhancement for furfural wastewater treatment, offering significant guidance for future research in this field.</p></div>","PeriodicalId":9929,"journal":{"name":"Chemical Engineering and Processing - Process Intensification","volume":"204 ","pages":"Article 109960"},"PeriodicalIF":3.8000,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental study on the treatment of furfural wastewater by ozone-Fenton coupling intensification\",\"authors\":\"Keyan Liu,&nbsp;Leiming Wang,&nbsp;Yifeng Han,&nbsp;Jinliang Tao,&nbsp;Feng Wei\",\"doi\":\"10.1016/j.cep.2024.109960\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Furfural production generates wastewater characterized by high concentration, strong acidity, and poor biodegradability, necessitating treatment before discharge. The Fenton process, known for its cost-effectiveness, is widely used for industrial wastewater treatment. However, it has limitations such as a narrow pH operating range and significant secondary pollution. To optimize this, researchers have explored combining Fenton with other processes, yet few have studied its synergy with O<sub>3</sub>. This study investigates the advantages of O<sub>3</sub>/Fenton coupling in treating furfural wastewater, comparing the capabilities of O<sub>3</sub>, O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub>, Fenton, and O<sub>3</sub>/Fenton processes. Results show that ozone-Fenton coupling exhibits superior industrial treatment performance. Post-treatment, the wastewater's B/C ratio reached 0.43, TOC removal rate was 33.6%, and ozone utilization efficiency was 74.6%, surpassing other methods. UV absorption spectra analysis indicated enhanced degradation of aromatic compounds, transforming them into smaller organic molecules. This study highlights ozone-Fenton coupling as a low-cost, effective enhancement for furfural wastewater treatment, offering significant guidance for future research in this field.</p></div>\",\"PeriodicalId\":9929,\"journal\":{\"name\":\"Chemical Engineering and Processing - Process Intensification\",\"volume\":\"204 \",\"pages\":\"Article 109960\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering and Processing - Process Intensification\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0255270124002988\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering and Processing - Process Intensification","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0255270124002988","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0

摘要

糠醛生产产生的废水具有高浓度、强酸性和生物降解性差的特点,需要在排放前进行处理。Fenton 工艺以其成本效益著称,被广泛用于工业废水处理。然而,它也有其局限性,如 pH 值操作范围窄和二次污染严重。为了优化这一问题,研究人员探索了 Fenton 与其他工艺的结合,但很少有人研究它与 O3 的协同作用。本研究通过比较 O3、O3/H2O2、Fenton 和 O3/Fenton 工艺的能力,探讨了 O3/Fenton 联用在处理糠醛废水中的优势。结果表明,臭氧-芬顿耦合工艺具有更优越的工业处理性能。处理后,废水的 B/C 比达到 0.43,TOC 去除率为 33.6%,臭氧利用率为 74.6%,超过了其他方法。紫外吸收光谱分析表明,芳香族化合物的降解能力增强,并转化为更小的有机分子。这项研究强调了臭氧-Fenton 耦合技术是一种低成本、有效的糠醛废水处理增强技术,为该领域的未来研究提供了重要指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Experimental study on the treatment of furfural wastewater by ozone-Fenton coupling intensification

Furfural production generates wastewater characterized by high concentration, strong acidity, and poor biodegradability, necessitating treatment before discharge. The Fenton process, known for its cost-effectiveness, is widely used for industrial wastewater treatment. However, it has limitations such as a narrow pH operating range and significant secondary pollution. To optimize this, researchers have explored combining Fenton with other processes, yet few have studied its synergy with O3. This study investigates the advantages of O3/Fenton coupling in treating furfural wastewater, comparing the capabilities of O3, O3/H2O2, Fenton, and O3/Fenton processes. Results show that ozone-Fenton coupling exhibits superior industrial treatment performance. Post-treatment, the wastewater's B/C ratio reached 0.43, TOC removal rate was 33.6%, and ozone utilization efficiency was 74.6%, surpassing other methods. UV absorption spectra analysis indicated enhanced degradation of aromatic compounds, transforming them into smaller organic molecules. This study highlights ozone-Fenton coupling as a low-cost, effective enhancement for furfural wastewater treatment, offering significant guidance for future research in this field.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
7.80
自引率
9.30%
发文量
408
审稿时长
49 days
期刊介绍: Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.
期刊最新文献
Phenomenological model of a reactive distillation column validated at pilot-plant scale to produce n-butyl lactate Ultra turrax-assisted extraction of Amazon oils: Optimization and comparison with Soxhlet and compressed propane extraction Insights into the nucleation mechanism of N2O bubble during the oxidation of alcohol-ketone oil by nitric acid in microreactors Eco-efficiency analysis and intensification of the monochlorobenzene separation process through vapor recompression strategy Intensified co-precipitation and ion exchange using an agitated tubular reactor (ATR) for enhanced removal of Cs+ and Sr2+ ions
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1