{"title":"CNT/CF/epoxy 界面的原位热拉曼绘图和应力分析","authors":"","doi":"10.1016/S1872-5805(24)60874-7","DOIUrl":null,"url":null,"abstract":"<div><p>A study of the interfacial behavior and internal thermal stress distribution in fiber-reinforced composites is essential to assess their performance and reliability. CNT/carbon fiber (CF) hybrid fibers were constructed using electrophoretic deposition. The interfacial properties of CF/epoxy and CNT/CF/epoxy composites were statistically investigated and compared using in-situ thermal Raman mapping by dispersing CNTs as a Raman sensing medium (CNTR) in a resin. The associated local thermal stress changes can be simulated by capturing the <em>G</em>‘ band position distribution of CNTR in the epoxy at different temperatures. It was found that the <em>G</em>‘ band shifted to lower positions with increasing temperature, reaching a maximum difference of 2.43 cm<sup>−1</sup> at 100 °C. The interfacial bonding between CNT/CF and the matrix and the stress distribution and changes during heat treatment (20–100 °C) were investigated in detail. This work is important for studying thermal stress in fiber-reinforced composites by in-situ thermal Raman mapping technology.</p></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":null,"pages":null},"PeriodicalIF":5.7000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In-situ thermal Raman mapping and stress analysis of CNT/CF/epoxy interfaces\",\"authors\":\"\",\"doi\":\"10.1016/S1872-5805(24)60874-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A study of the interfacial behavior and internal thermal stress distribution in fiber-reinforced composites is essential to assess their performance and reliability. CNT/carbon fiber (CF) hybrid fibers were constructed using electrophoretic deposition. The interfacial properties of CF/epoxy and CNT/CF/epoxy composites were statistically investigated and compared using in-situ thermal Raman mapping by dispersing CNTs as a Raman sensing medium (CNTR) in a resin. The associated local thermal stress changes can be simulated by capturing the <em>G</em>‘ band position distribution of CNTR in the epoxy at different temperatures. It was found that the <em>G</em>‘ band shifted to lower positions with increasing temperature, reaching a maximum difference of 2.43 cm<sup>−1</sup> at 100 °C. The interfacial bonding between CNT/CF and the matrix and the stress distribution and changes during heat treatment (20–100 °C) were investigated in detail. This work is important for studying thermal stress in fiber-reinforced composites by in-situ thermal Raman mapping technology.</p></div>\",\"PeriodicalId\":19719,\"journal\":{\"name\":\"New Carbon Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Carbon Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1872580524608747\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Carbon Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1872580524608747","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
In-situ thermal Raman mapping and stress analysis of CNT/CF/epoxy interfaces
A study of the interfacial behavior and internal thermal stress distribution in fiber-reinforced composites is essential to assess their performance and reliability. CNT/carbon fiber (CF) hybrid fibers were constructed using electrophoretic deposition. The interfacial properties of CF/epoxy and CNT/CF/epoxy composites were statistically investigated and compared using in-situ thermal Raman mapping by dispersing CNTs as a Raman sensing medium (CNTR) in a resin. The associated local thermal stress changes can be simulated by capturing the G‘ band position distribution of CNTR in the epoxy at different temperatures. It was found that the G‘ band shifted to lower positions with increasing temperature, reaching a maximum difference of 2.43 cm−1 at 100 °C. The interfacial bonding between CNT/CF and the matrix and the stress distribution and changes during heat treatment (20–100 °C) were investigated in detail. This work is important for studying thermal stress in fiber-reinforced composites by in-situ thermal Raman mapping technology.
期刊介绍：
New Carbon Materials is a scholarly journal that publishes original research papers focusing on the physics, chemistry, and technology of organic substances that serve as precursors for creating carbonaceous solids with aromatic or tetrahedral bonding. The scope of materials covered by the journal extends from diamond and graphite to a variety of forms including chars, semicokes, mesophase substances, carbons, carbon fibers, carbynes, fullerenes, and carbon nanotubes. The journal's objective is to showcase the latest research findings and advancements in the areas of formation, structure, properties, behaviors, and technological applications of carbon materials. Additionally, the journal includes papers on the secondary production of new carbon and composite materials, such as carbon-carbon composites, derived from the aforementioned carbons. Research papers on organic substances will be considered for publication only if they have a direct relevance to the resulting carbon materials.
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