废塑料瓶是合成具有潜在应用价值的金属有机框架(MOFs)的替代材料

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引用次数: 0

摘要

聚对苯二甲酸乙二醇酯(PET)废物,尤其是源自消费后瓶子的废物,由于其广泛使用和生物降解性不足,对环境造成了严重危害。为了解决与塑料废弃物相关的日益严重的环境问题,制定可持续的回收和利用战略至关重要。本研究探讨了利用废弃塑料瓶(特别是 PET)作为前体合成金属有机框架(MOFs)的潜力。合成过程包括对 PET 进行解聚,生成对苯二甲酸,作为形成 MOF 的有机连接体。对 PET 衍生 MOFs 的潜在应用进行了分析,包括催化、吸附和气体分离。综述还强调了该领域的前景和挑战,强调了进一步完善、扩展和商业化 PET 源 MOFs 的必要性。其总体目标是促进采用对生态负责的方法来管理废塑料,并通过 MOF 合成创造有价值的材料。
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Waste plastic bottles an alternate material for synthesis of metal organic frameworks (MOFs) with potential applications

Polyethylene terephthalate (PET) waste, especially originating from post-consumer bottles, represents a significant environmental hazard owing to its widespread utilization and inadequate biodegradability. Addressing the growing environmental issues associated with plastic waste, the development of sustainable strategies for recycling and utilization is of paramount importance. This study explores the potential of employing waste plastic bottles, specifically PET, as a precursor in the synthesis of Metal-Organic Frameworks (MOFs). The synthesis procedure encompasses the depolymerization of PET to yield terephthalic acid, serving as an organic linker in the formation of MOFs. An analysis of the potential applications of PET-derived MOFs, including catalysis, adsorption, and gas separation, is conducted. The review also highlights prospects and challenges within the field, underscoring the necessity for further refinement, scalability, and commercialization of PET-sourced MOFs. The overarching aim is to foster the advancement of ecologically responsible methods for waste plastic management and the creation of valuable materials through MOF synthesis.

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