在贫氢预混合小火焰中通过强化应变缓解优先扩散效应

IF 5.3 2区 工程技术 Q2 ENERGY & FUELS Proceedings of the Combustion Institute Pub Date : 2024-08-22 DOI:10.1016/j.proci.2024.105728
Alessandro Porcarelli, Ivan Langella
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引用次数: 0

摘要

本研究以数值方法研究了贫氢预混合小火焰中应变和优先扩散之间的相互作用。贫化条件设定为等效比 0.5。对反应物-生成物逆流配置进行了详细的化学一维模拟,既包括优先扩散效应,也人为地排除了优先扩散效应。对火焰物理特性进行的综合分析表明,与人为抑制优先扩散的情况相比,优先扩散往往会削弱火焰,因为它会引发火焰前沿混合物的局部倾斜。与直觉相反的是,应变会抵消或限制这种优先扩散效应,随着应变的增加,自由基和反应速率、火焰厚度和消耗速度的峰值会逐渐接近并在某些情况下超过在同等扩散率下得到的相应解决方案。这是因为流体元素越来越倾向于在火焰切线方向上传输,而不是在火焰法线方向上扩散。因此,由于燃料和氧化剂在火焰前沿的扩散通量不同而导致的火焰减弱效应,会逐渐被它们在火焰切向方向上的差分传输所补偿,而这种差分传输是由应用应变率的增加所引发的,这反而会使燃烧混合物整体富集。与之前认为应变会增强优先扩散效应的研究相比,这一分析提供了不同的观点。本研究提出了相反的解释,即应变是削弱贫氢火焰优先扩散效应的限制因素。
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Mitigation of preferential diffusion effects by intensive strain in lean premixed hydrogen flamelets
The interplay between strain and preferential diffusion in lean premixed hydrogen flamelets is investigated numerically. Lean conditions are established at an equivalence ratio of 0.5. Detailed chemistry, one-dimensional simulations are performed on a reactants-to-products counterflow configuration, both including and artificially excluding preferential diffusion effects. A comprehensive analysis of the flame physical properties is performed, showing that preferential diffusion tends to weaken the flame as compared to the case where it is artificially suppressed, as it triggers a local leaning of the mixture ahead of the flame front. Counterintuitively, strain is observed to counteract or limit this preferential diffusion effect, with the peaks of radicals and reaction rate, flame thickness, and consumption speed, progressively approaching and in some cases overtaking the corresponding solution obtained with equal diffusivities as strain increases. This is shown to be a consequence of the fluid elements being increasingly preferentially transported in the flame tangential direction rather than diffusing in the flame normal direction. Hence, the flame weakening effect due to different diffusive fluxes of fuel and oxidizer across the flame front is progressively compensated by their differential transport on the flame tangential direction triggered by increasing applied strain rate, which instead enables an overall enrichment of the burning mixture. This analysis provides a different view as compared to previous studies attributing to strain an enhancing influence on the effects of preferential diffusion. In this work the opposite interpretation is proposed instead, where strain acts as a limiting factor to the weakening effect of preferential diffusion on lean hydrogen flames.
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来源期刊
Proceedings of the Combustion Institute
Proceedings of the Combustion Institute 工程技术-工程:化工
CiteScore
7.00
自引率
0.00%
发文量
420
审稿时长
3.0 months
期刊介绍: The Proceedings of the Combustion Institute contains forefront contributions in fundamentals and applications of combustion science. For more than 50 years, the Combustion Institute has served as the peak international society for dissemination of scientific and technical research in the combustion field. In addition to author submissions, the Proceedings of the Combustion Institute includes the Institute''s prestigious invited strategic and topical reviews that represent indispensable resources for emergent research in the field. All papers are subjected to rigorous peer review. Research papers and invited topical reviews; Reaction Kinetics; Soot, PAH, and other large molecules; Diagnostics; Laminar Flames; Turbulent Flames; Heterogeneous Combustion; Spray and Droplet Combustion; Detonations, Explosions & Supersonic Combustion; Fire Research; Stationary Combustion Systems; IC Engine and Gas Turbine Combustion; New Technology Concepts The electronic version of Proceedings of the Combustion Institute contains supplemental material such as reaction mechanisms, illustrating movies, and other data.
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