金属 Zr 表面激光镀层 Cr-xAl 的高温抗氧化、抗腐蚀和抗磨损性能

IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Engineering and Performance Pub Date : 2024-09-06 DOI:10.1007/s11665-024-09982-7
Jianguo Cheng, Chaoqun Xia, Bo Yang, Xiaojun Jiang, Hua Zhong, Tianshuo Song, Shuguang Liu, Tai Yang, Qiang Li
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摘要

带有激光熔融铬涂层的 Zr 合金具有优异的抗高温氧化性能,被广泛应用于核工业。为了研究添加 Al 对涂层的高温氧化性能、耐腐蚀性和耐磨性的影响,使用激光熔覆技术在纯 Zr 表面镀上了不同 Al 含量的 Cr-xAl 涂层。研究结果表明,激光熔覆涂层显示出涂层与基体之间良好的相互扩散性。涂层的硬度和厚度随铝含量的增加而增加,但涂层的质量随铝元素的增加而降低。通过比较不同样品在 800-1100 °C 下的高温氧化增重曲线和形貌可以看出,Cr-xAl 涂层的氧化增重约为未涂层基体的一半,表现出优异的高温抗氧化性。从摩擦形貌和体积损失得出的结论表明,Cr 和 Cr90Al10 涂层的磨损体积约为基体的 1/5,与基体相比,耐磨性显著提高。
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High-Temperature Oxidation, Corrosion, and Wear Resistance of Cr‐xAl Laser Coated on Metal Zr Surface

Zr alloy with laser-melted Cr coatings exhibits excellent resistance to high-temperature oxidation and are widely used in the nuclear industry. To examine the impact of adding Al on the high-temperature oxidation performance, corrosion, and wear resistance of the coatings, Cr-xAl coatings with varying Al contents were applied to the pure Zr surface using laser cladding. Research results show that laser cladding coatings reveal good interdiffusion between the coatings and the substrate. The hardness and thickness of the coatings increase with the increase in Al content, but the quality of the coatings decreases with the increase of Al elements. A comparison of the high-temperature oxidation weight gain curve and morphology of different samples at 800–1100 °C shows that the oxidation weight gain of Cr-xAl coatings is about half of that of the uncoated substrate, exhibiting excellent high-temperature oxidation resistance. Conclusions drawn from friction morphology and volume loss indicate that the wear volume of Cr and Cr90Al10 coatings is approximately 1/5 of the substrate, demonstrating significantly improved wear resistance compared to the substrate.

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来源期刊
Journal of Materials Engineering and Performance
Journal of Materials Engineering and Performance 工程技术-材料科学:综合
CiteScore
3.90
自引率
13.00%
发文量
1120
审稿时长
4.9 months
期刊介绍: ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance. The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication. Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered
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