Sheikh Joifullah, Md. Adil Hossain, Maruf Al Yeamin, Md. Mahfuzul Haque, Redi Kristian Pingak, Noorhan F. AlShaikh Mohammad, Mohammed S. Abu-Jafar, Ahmad A. Mousa, Asif Hosen
{"title":"用于增强光电应用的 Sr3PX3(X = Cl、Br)压力调制结构、电子、机械和光学特性的第一性原理研究","authors":"Sheikh Joifullah, Md. Adil Hossain, Maruf Al Yeamin, Md. Mahfuzul Haque, Redi Kristian Pingak, Noorhan F. AlShaikh Mohammad, Mohammed S. Abu-Jafar, Ahmad A. Mousa, Asif Hosen","doi":"10.1007/s11082-024-07388-2","DOIUrl":null,"url":null,"abstract":"<p>This study investigates the influence of hydrostatic pressure on structural, electronic, mechanical and optical properties of Sr<sub>3</sub>PX<sub>3</sub> (X = Cl and Br) compounds, by using the first-principles density functional theory (DFT) within the pressure range of 0–30 GPa with a span of 10 GPa. For Sr₃PCl₃ and Sr<sub>3</sub>PBr<sub>3</sub>, the dynamical stability is confirmed by the fact that the phonon dispersion curves do not contain imaginary modes. Pressure-induced band gap alterations in Sr<sub>3</sub>PCl<sub>3</sub> and Sr<sub>3</sub>PBr<sub>3</sub> reveal semiconducting behavior: GGA measurements show a decrease from 1.70 eV and 1.55 eV at ambient pressure to 0.22 eV and 0.21 eV at 30 GPa; TB-mBJ results show a decrease from 2.73 eV and 2.40 to 1.07 eV and 0.92 eV. This supports their inverse relationship with pressure. The values of Debye and melting temperatures support their high-temperature applications. Effective mass also shows an inverse relationship with induced pressure. The bond length, lattice parameters, and cell volume reduces with pressure. They exhibit ductility, which is further enhanced by the applied pressure. These materials emerge as promising candidates for flexible optoelectronic devices. Optical properties like absorption coefficients, reflectivity, and dielectric functions were observed and found to be significantly influenced by applied pressure. The absorption spectra exhibit a significant redshift with increasing pressure, indicating enhanced potential for optoelectronic applications. Our detailed investigation sheds light on the tunability of Sr<sub>3</sub>PX<sub>3</sub> (X = Cl and Br) properties under pressure, showcasing their potential for cutting-edge applications in optoelectronics and photovoltaics.</p>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":null,"pages":null},"PeriodicalIF":3.3000,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"First-principles investigation of pressure-modulated structural, electronic, mechanical, and optical characteristics of Sr3PX3 (X = Cl, Br) for enhanced optoelectronic application\",\"authors\":\"Sheikh Joifullah, Md. Adil Hossain, Maruf Al Yeamin, Md. Mahfuzul Haque, Redi Kristian Pingak, Noorhan F. AlShaikh Mohammad, Mohammed S. Abu-Jafar, Ahmad A. Mousa, Asif Hosen\",\"doi\":\"10.1007/s11082-024-07388-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study investigates the influence of hydrostatic pressure on structural, electronic, mechanical and optical properties of Sr<sub>3</sub>PX<sub>3</sub> (X = Cl and Br) compounds, by using the first-principles density functional theory (DFT) within the pressure range of 0–30 GPa with a span of 10 GPa. For Sr₃PCl₃ and Sr<sub>3</sub>PBr<sub>3</sub>, the dynamical stability is confirmed by the fact that the phonon dispersion curves do not contain imaginary modes. Pressure-induced band gap alterations in Sr<sub>3</sub>PCl<sub>3</sub> and Sr<sub>3</sub>PBr<sub>3</sub> reveal semiconducting behavior: GGA measurements show a decrease from 1.70 eV and 1.55 eV at ambient pressure to 0.22 eV and 0.21 eV at 30 GPa; TB-mBJ results show a decrease from 2.73 eV and 2.40 to 1.07 eV and 0.92 eV. This supports their inverse relationship with pressure. The values of Debye and melting temperatures support their high-temperature applications. Effective mass also shows an inverse relationship with induced pressure. The bond length, lattice parameters, and cell volume reduces with pressure. They exhibit ductility, which is further enhanced by the applied pressure. These materials emerge as promising candidates for flexible optoelectronic devices. Optical properties like absorption coefficients, reflectivity, and dielectric functions were observed and found to be significantly influenced by applied pressure. The absorption spectra exhibit a significant redshift with increasing pressure, indicating enhanced potential for optoelectronic applications. Our detailed investigation sheds light on the tunability of Sr<sub>3</sub>PX<sub>3</sub> (X = Cl and Br) properties under pressure, showcasing their potential for cutting-edge applications in optoelectronics and photovoltaics.</p>\",\"PeriodicalId\":720,\"journal\":{\"name\":\"Optical and Quantum Electronics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical and Quantum Electronics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s11082-024-07388-2\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical and Quantum Electronics","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s11082-024-07388-2","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
摘要
本研究采用第一原理密度泛函理论(DFT),在 0-30 GPa 压力范围内(跨度为 10 GPa)研究了静水压力对 Sr3PX3(X = Cl 和 Br)化合物的结构、电子、机械和光学特性的影响。对于 Sr₃PCl₃和 Sr3PBr3,声子色散曲线不包含虚模的事实证实了其动力学稳定性。在 Sr3PCl3 和 Sr3PBr3 中,压力引起的带隙变化揭示了半导体行为:GGA 测量结果表明,在环境压力下,它们的带隙分别从 1.70 eV 和 1.55 eV 下降到 30 GPa 时的 0.22 eV 和 0.21 eV;TB-mBJ 结果表明,它们的带隙分别从 2.73 eV 和 2.40 下降到 1.07 eV 和 0.92 eV。这证明了它们与压力的反比关系。德拜温度和熔化温度值支持它们在高温下的应用。有效质量也显示出与诱导压力的反比关系。键长、晶格参数和晶胞体积随压力而减小。它们表现出延展性,并通过施加压力进一步增强。这些材料有望成为柔性光电器件的候选材料。对吸收系数、反射率和介电函数等光学特性进行了观察,发现它们受外加压力的影响很大。随着压力的增加,吸收光谱会出现明显的红移,这表明光电应用的潜力得到了增强。我们的详细研究揭示了 Sr3PX3(X = Cl 和 Br)在压力下的可调谐性,展示了它们在光电子和光伏领域的尖端应用潜力。
First-principles investigation of pressure-modulated structural, electronic, mechanical, and optical characteristics of Sr3PX3 (X = Cl, Br) for enhanced optoelectronic application
This study investigates the influence of hydrostatic pressure on structural, electronic, mechanical and optical properties of Sr3PX3 (X = Cl and Br) compounds, by using the first-principles density functional theory (DFT) within the pressure range of 0–30 GPa with a span of 10 GPa. For Sr₃PCl₃ and Sr3PBr3, the dynamical stability is confirmed by the fact that the phonon dispersion curves do not contain imaginary modes. Pressure-induced band gap alterations in Sr3PCl3 and Sr3PBr3 reveal semiconducting behavior: GGA measurements show a decrease from 1.70 eV and 1.55 eV at ambient pressure to 0.22 eV and 0.21 eV at 30 GPa; TB-mBJ results show a decrease from 2.73 eV and 2.40 to 1.07 eV and 0.92 eV. This supports their inverse relationship with pressure. The values of Debye and melting temperatures support their high-temperature applications. Effective mass also shows an inverse relationship with induced pressure. The bond length, lattice parameters, and cell volume reduces with pressure. They exhibit ductility, which is further enhanced by the applied pressure. These materials emerge as promising candidates for flexible optoelectronic devices. Optical properties like absorption coefficients, reflectivity, and dielectric functions were observed and found to be significantly influenced by applied pressure. The absorption spectra exhibit a significant redshift with increasing pressure, indicating enhanced potential for optoelectronic applications. Our detailed investigation sheds light on the tunability of Sr3PX3 (X = Cl and Br) properties under pressure, showcasing their potential for cutting-edge applications in optoelectronics and photovoltaics.
期刊介绍:
Optical and Quantum Electronics provides an international forum for the publication of original research papers, tutorial reviews and letters in such fields as optical physics, optical engineering and optoelectronics. Special issues are published on topics of current interest.
Optical and Quantum Electronics is published monthly. It is concerned with the technology and physics of optical systems, components and devices, i.e., with topics such as: optical fibres; semiconductor lasers and LEDs; light detection and imaging devices; nanophotonics; photonic integration and optoelectronic integrated circuits; silicon photonics; displays; optical communications from devices to systems; materials for photonics (e.g. semiconductors, glasses, graphene); the physics and simulation of optical devices and systems; nanotechnologies in photonics (including engineered nano-structures such as photonic crystals, sub-wavelength photonic structures, metamaterials, and plasmonics); advanced quantum and optoelectronic applications (e.g. quantum computing, memory and communications, quantum sensing and quantum dots); photonic sensors and bio-sensors; Terahertz phenomena; non-linear optics and ultrafast phenomena; green photonics.