Du Zhou , Chaozheng Ding , Weijie Han , Huibing Li , Haitao Zhang , Wentao Xu , Youfu Zhou
{"title":"通过水热纳米粉体低温制备氧化锆透明陶瓷","authors":"Du Zhou , Chaozheng Ding , Weijie Han , Huibing Li , Haitao Zhang , Wentao Xu , Youfu Zhou","doi":"10.1016/j.ceramint.2024.09.263","DOIUrl":null,"url":null,"abstract":"<div><div>Highly sinterable nanopowder of 8 mol% yttria-stabilized cubic zirconia (8YSZ) was synthesized via a hydrothermal homogeneous precipitation (HHP) method. The nanopowder with an average particle size of 26 nm, exhibits good dispersibility, narrow particle size distribution and high purity, making it ideal raw material for preparing transparent ceramics. Utilizing spark plasma sintering (SPS) under mild conditions (1200–1350 °C, 80 MPa, 10 min) in contrast to hot isostatic pressing (HIP), cubic zirconia ceramics with favorable optical and mechanical properties were produced. The sample sintered at 1250 °C achieved the highest transmittance of 74 %@850 nm, significantly surpassing the performance of samples prepared from two other commercial 8YSZ powders. Furthermore, the specimen sintered at 1200 °C with a dense fine microstructure (relative density: 99.51 %, grain size: 460 nm), demonstrated the highest hardness and fracture toughness, reaching 15.72 GPa and 1.28 MPa m<sup>1/2</sup>, respectively.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 49210-49216"},"PeriodicalIF":5.1000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Low-temperature fabrication of zirconia transparent ceramics via hydrothermal nanopowder\",\"authors\":\"Du Zhou , Chaozheng Ding , Weijie Han , Huibing Li , Haitao Zhang , Wentao Xu , Youfu Zhou\",\"doi\":\"10.1016/j.ceramint.2024.09.263\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Highly sinterable nanopowder of 8 mol% yttria-stabilized cubic zirconia (8YSZ) was synthesized via a hydrothermal homogeneous precipitation (HHP) method. The nanopowder with an average particle size of 26 nm, exhibits good dispersibility, narrow particle size distribution and high purity, making it ideal raw material for preparing transparent ceramics. Utilizing spark plasma sintering (SPS) under mild conditions (1200–1350 °C, 80 MPa, 10 min) in contrast to hot isostatic pressing (HIP), cubic zirconia ceramics with favorable optical and mechanical properties were produced. The sample sintered at 1250 °C achieved the highest transmittance of 74 %@850 nm, significantly surpassing the performance of samples prepared from two other commercial 8YSZ powders. Furthermore, the specimen sintered at 1200 °C with a dense fine microstructure (relative density: 99.51 %, grain size: 460 nm), demonstrated the highest hardness and fracture toughness, reaching 15.72 GPa and 1.28 MPa m<sup>1/2</sup>, respectively.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 49210-49216\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224042718\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224042718","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Low-temperature fabrication of zirconia transparent ceramics via hydrothermal nanopowder
Highly sinterable nanopowder of 8 mol% yttria-stabilized cubic zirconia (8YSZ) was synthesized via a hydrothermal homogeneous precipitation (HHP) method. The nanopowder with an average particle size of 26 nm, exhibits good dispersibility, narrow particle size distribution and high purity, making it ideal raw material for preparing transparent ceramics. Utilizing spark plasma sintering (SPS) under mild conditions (1200–1350 °C, 80 MPa, 10 min) in contrast to hot isostatic pressing (HIP), cubic zirconia ceramics with favorable optical and mechanical properties were produced. The sample sintered at 1250 °C achieved the highest transmittance of 74 %@850 nm, significantly surpassing the performance of samples prepared from two other commercial 8YSZ powders. Furthermore, the specimen sintered at 1200 °C with a dense fine microstructure (relative density: 99.51 %, grain size: 460 nm), demonstrated the highest hardness and fracture toughness, reaching 15.72 GPa and 1.28 MPa m1/2, respectively.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.