Fabrication and anti-fouling performance assessment of micro-textured CNT-PDMS nanocomposites through the scalable roll-coating process.

This study investigates the micro-topographic surfaces as a benign anti-fouling/fouling-release method. The bio-inspired engineered surfaces were manufactured by controlling the viscoelastic instabilities of carbon nanotubes (CNTs) and polydimethylsiloxane (PDMS) nanocomposites using a customized, scalable two-roll coating process. The effects of manufacturing conditions, i.e., roller speed and roller radius-to-gap ratio, on surface properties, such as Wenzel roughness factor, peak density, water contact angle, and the tensile testing of the nanocomposite, were studied. The results showed that decreasing roller gap distance would significantly increase the hydrophobicity of the samples. Moreover, a positive correlation was observed between surface peak density and roughness factor. A textured sample was manufactured that significantly outperformed the non-textured CNT-PDMS, indicating a correlation between surface roughness and diatom attachment density. The dynamic diatom attachment assay showed up to 35% reduction in surface coverage of textured samples by the Navicula perminuta diatom compared to the non-textured CNT-PDMS control samples.