老化粘弹性悬浮液径向位移形成界面图案的生长动力学

Q3 Materials Science JCIS open Pub Date : 2023-07-01 DOI:10.1016/j.jciso.2023.100084
Palak, Vaibhav Raj Singh Parmar, Ranjini Bandyopadhyay
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引用次数: 3

摘要

当一个柔软的玻璃状胶体悬浮液被径向Hele-Shaw几何形状的牛顿流体置换时,在界面处形成的模式形态是由前者的复杂流变学决定的。我们在早期的工作中报道过[Palak, V. R. S. Parmar, D. Saha和R. Bandyopadhyay, JCIS Open, 6(2022) 100047],通过控制置换悬浮液的弹性、置换流体的流速和流体对的界面张力,可以形成一系列具有独特结构特征的模式形态。有趣的是,所有不同的形态特征都可以通过它们的面积比来区分,面积比的定义是完全发育的图案所占的面积与包围它的最小圆圈的面积之比。在这项早期工作的基础上,我们在这里表明,对时空模式生长的系统研究可以揭示模式选择机制的重要信息。我们分析了这些图案的时间演化,揭示了它们的生长机制和完全发育的形态之间有趣的相关性。我们相信,这种对老化粘弹性粘土悬浮液和牛顿流体之间界面模式生长的独特时间特征的系统识别,有助于预防和抑制泥浆和水泥浆置换过程中界面不稳定性的发生和演变。
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Growth kinetics of interfacial patterns formed by the radial displacement of an aging viscoelastic suspension

When a soft glassy colloidal suspension is displaced by a Newtonian fluid in a radial Hele-Shaw geometry, the pattern morphology that develops at the interface is determined by the complex rheology of the former. We had reported in an earlier work [Palak, V. R. S. Parmar, D. Saha and R. Bandyopadhyay, JCIS Open, 6 (2022) 100047] that a range of pattern morphologies characterised by distinctive structural features can be formed by controlling the elasticity of the displaced suspension, the flow rate of the displacing fluid and the interfacial tension of the fluid pair. Interestingly, all the different morphological features can be distinguished in terms of their areal ratios, defined as the ratio of the areas occupied by the fully-developed pattern and the smallest circle enclosing it. In a significant advance to this earlier work, we show here that a systematic study of spatio-temporal pattern growth can reveal important information about pattern selection mechanisms. We analyse the time-evolution of the patterns to reveal interesting correlations between their growth mechanisms and fully-developed morphologies. We believe that such systematic identification of the unique temporal features characterising pattern growth at the interface between an aging viscoelastic clay suspension and a Newtonian fluid can be useful in pre-empting and suppressing the onset and evolution of interfacial instabilities in the displacement of mud and cement slurries.

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来源期刊
JCIS open
JCIS open Physical and Theoretical Chemistry, Colloid and Surface Chemistry, Surfaces, Coatings and Films
CiteScore
4.10
自引率
0.00%
发文量
0
审稿时长
36 days
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