{"title":"新型含钾银矾型化合物的合成与表征","authors":"I. Studenyak","doi":"10.15407/SPQEO22.01.026","DOIUrl":null,"url":null,"abstract":"Potassium halogenthiophosphates K6PS5Br and K6PS5Cl as well as halogen-free K7PS6 compound were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectroscopy. Raman spectra of K6PS5Br and K6PS5Cl show themselves to be much similar to those of chemically related Cu6PS5Br and Cu6PS5Cl argyrodite crystals. The much richer spectra of K6PS5Br and K6PS5Cl as well as K7PS6, however, reveal that their structure most likely differs from the cubic structure of Cu6PS5Br and Cu6PS5Cl argyrodites. doi: https://doi.org/10.15407/spqeo22.01.26 PACS 78.40.Ha; 77.80.Bh","PeriodicalId":44695,"journal":{"name":"Semiconductor Physics Quantum Electronics & Optoelectronics","volume":" ","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2019-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Synthesis and characterization of new potassium-containing argyrodite-type compounds\",\"authors\":\"I. Studenyak\",\"doi\":\"10.15407/SPQEO22.01.026\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Potassium halogenthiophosphates K6PS5Br and K6PS5Cl as well as halogen-free K7PS6 compound were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectroscopy. Raman spectra of K6PS5Br and K6PS5Cl show themselves to be much similar to those of chemically related Cu6PS5Br and Cu6PS5Cl argyrodite crystals. The much richer spectra of K6PS5Br and K6PS5Cl as well as K7PS6, however, reveal that their structure most likely differs from the cubic structure of Cu6PS5Br and Cu6PS5Cl argyrodites. doi: https://doi.org/10.15407/spqeo22.01.26 PACS 78.40.Ha; 77.80.Bh\",\"PeriodicalId\":44695,\"journal\":{\"name\":\"Semiconductor Physics Quantum Electronics & Optoelectronics\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2019-03-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Semiconductor Physics Quantum Electronics & Optoelectronics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15407/SPQEO22.01.026\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"QUANTUM SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Semiconductor Physics Quantum Electronics & Optoelectronics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15407/SPQEO22.01.026","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"QUANTUM SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Synthesis and characterization of new potassium-containing argyrodite-type compounds
Potassium halogenthiophosphates K6PS5Br and K6PS5Cl as well as halogen-free K7PS6 compound were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectroscopy. Raman spectra of K6PS5Br and K6PS5Cl show themselves to be much similar to those of chemically related Cu6PS5Br and Cu6PS5Cl argyrodite crystals. The much richer spectra of K6PS5Br and K6PS5Cl as well as K7PS6, however, reveal that their structure most likely differs from the cubic structure of Cu6PS5Br and Cu6PS5Cl argyrodites. doi: https://doi.org/10.15407/spqeo22.01.26 PACS 78.40.Ha; 77.80.Bh
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
