改性聚丙烯酰胺驱油性能的研究

A. B. Issa, O. K. Beissenbayev, A.Sh. Kydyraliyeva, M. Yessirkepova, E. A. Tussupkalyiev, Zh. N. Kainarbayeva, Issa Aziza Bakytzhankyzy, Oral Kurganbekovich, Kydyraliyeva Aigul, Yessirkepova Maral, Mahmudovna, Tussupkaliyev Ersin, Adiyetovich, Nurbekovna
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摘要

目前,表面活性剂和水溶性聚电解质作为稳定剂和选择性剂的使用,与世界化工、石油等行业技术问题的成功解决有着千丝万缕的联系。本工作的目的是在过硫酸钾和硫酸钠的存在下,用棉酚树脂合成改性聚丙烯酰胺,并进一步交联以取代油,研究改性聚丙烯酰胺的理化性能。方法。为了确定改性PAA的光谱特性,在红外-傅立叶光谱仪上进行了红外光谱分析。结构元素组成(SEM)采用Jeol JSM-6490l V电子显微镜。用Ubellode悬挂式毛细管粘度计测定了改性PAA溶液的粘度。结果和讨论。由聚合物复合材料胶体化学性质研究的作者进行的研究,使我们能够得出这样的结论:在氢氧化钠蒸馏过程中水解脂肪酸的还原残渣,并在过硫酸钾和硫酸钠的存在下进一步交联,得到的试剂具有良好的表面活性和乳化性能,这在从层中驱油时很重要。研究了聚合物组合物的表面张力。随着溶液浓度的增加,表面张力减小,即表面活性增加。结论。研究结果表明,注入聚合物试剂溶液可使驱油效率提高6 ~ 7%。
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INVESTIGATION OF MODIFIED POLYACRYLAMIDE FOR OIL DISPLACEMENT
At present, the use of surfactants and water-soluble polyelectrolytes, which act as stabilizing and selective agents, is inextricably linked with the successful solution of the technological issues in the world of chemical, oil and other industries. The purpose of the work is to synthesize and study the physicochemical properties of modified polyacrylamide with gossypol resin and further crosslinking in the presence of potassium persulfate and sodium sulphate to displace oil. Methods. To establish the spectral characteristics of the modified PAA, IR spectra have been taken on an IR-Fourier spectrometer. For the structural-elemental composition (SEM), a Jeol JSM-6490l V electron microscope has been used. The viscosity of modified PAA solutions has been measured in a Ubellode capillary viscometer with a hanging level. Results and discussion. The studies, carried out by the authors of the study of the colloid-chemical properties of polymer composites, allow us to conclude that the reagents obtained during the hydrolysis of vat residues of fatty acids distillation with sodium hydroxide with further cross-linking in the presence of potassium persulfate and sodium sulphate have good surfaceactive and emulsifying properties, which is important when displacing oil from layers. The surface tension of polymer compositions has been studied. With an increase in the concentration of the solution, the surface tension decreases, i.e., the surface activity increases. Conclusion. The research results show that the injection of a polymer reagent solution can increase the oil displacement efficiency by 6-7%.
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