改性剂对润湿矿物填料过程及沥青膜疏水性影响的研究

A. Dyuryagina, YU.S. Byzova, N. Salikova, K. Ostrovnoy, T. A. Gorshkova, P.O. Savelyeva
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摘要

如你所知,沥青路面的质量经常达不到规定的标准。沥青与矿物材料之间的粘附程度低,主要是由于沥青不能有效润湿碎石表面,特别是酸性碎石。本工作的目的是确定各种改性剂对沥青组分润湿过程的影响。研究方法包括根据沥青中聚合物的定量含量,研究不同性质的矿物填料的润湿过程,以及改性剂对沥青膜疏水性影响的规律。用躺滴法实验确定了表面的润湿角θ。结果与讨论:通过对所得数据的分析,AG-4I的引入对降低“沥青组分-灰色碎石”相界面表面张力σlga的作用最为有效。这是由该组合物的最大润湿能力证明的。结论:在两种聚合物改性剂中,废密封液AG-4I对矿物填料润湿过程和沥青膜疏水性的影响最大。在较窄的改性剂浓度范围内(Cmodif= 0.5%),沥青组分的防水性得到增强。与AG-4I相媲美的疏水效应可以将0.25%的氯化钙引入沥青成分中。
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STUDY OF THE INFLUENCE OF MODIFIERS ON THE PROCESSES OF WETTING MINERAL FILLERS AND HYDROPHOBICITY OF BITUMEN FILMS
As you know, the quality of asphalt pavement often does not meet the stated standards. The low degree of adhesion between bitumen and mineral material is primarily due to the insufficient ability of bitumen to effectively wet the surface of crushed stone, especially of an acidic nature. The aim of the work is to establish the influence of various modifiers on the wetting processes of bitumen compositions. The methods of the work included the study of the wetting processes of mineral fillers of various nature depending on the quantitative polymer content in bitumen, as well as the study of the regularities of the effect of modifiers on the hydrophobicity of bitumen films. The wetting angle θof the surface was experimentally determined by the lying drop method. Results and discussion: as follows from the analysis of the data obtained, the introduction of AG-4I most effectively contributes to the reduction of the surface tension σlgat the interface of the phases "bitumen composition –gray crushed stone". This is evidenced by the maximum wetting ability of the composition. Conclusion: it was found that of the two polymer modifiers, the spent sealing liquid AG-4I has the maximum effect on the wetting processes of mineral fillers and the hydrophobicity of bitumen films. A narrow range of modifier concentrations (Cmodif= 0.5%) was revealed, at which the water-repellent properties of bitumen compositions are enhanced. A hydrophobic effect comparable to AG-4I provides the introduction of 0.25% calcium chloride into the bitumen composition.
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