正硅酸四乙酯浓度优化钙钛矿太阳能电池性能

M. Isa, J. Sulistianto, Rembianov, L. Kevin, N. R. Poespawati
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引用次数: 2

摘要

钙钛矿太阳能电池(PSC)是一种使用有机无机卤化物形成活性物质的太阳能电池。在过去的10年里,PSCs发展迅速,效率提高了22.11%。然而,用于PSC开发的有机化合物往往不能表现出对水分和氧气的强大抵抗力,从而导致细胞快速降解。为了弥补其在制造过程中暴露于水分和氧气以及存在环境空气的操作时间时的弱特性,陷阱钝化是一种可以用来防止由活性电池层间表面的不均匀性引起的电荷陷阱状态的方法。本文将正硅酸四乙酯(TEOS)在钙钛矿活性层中施加3种浓度,以确定哪种浓度能获得最佳的钙钛矿太阳能电池Voc、Isc和填充系数。在本研究中,我们在钙钛矿活性层中添加0.3%mol的TEOS添加剂,其Voc、Isc和FF值分别为0.76 V、3.96 mA和0.4563,获得了最佳效果。
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Optimization of Perovskite Solar Cell Performance using Optimized Level of Tetraethyl Orthosilicate Concentration
Perovskite solar cell (PSC) is a type of solar cell in which the active material is formed using an organicinorganic halide. PSCs have shown rapid development over the past 10 years with an increase of efficiency up to 22.11%. However, organic compounds used in the development of PSC have often failed to show strong resistance towards moisture and oxygen, thus resulting in rapid cell degradation. In order to compensate for its weak characteristics when exposed to moisture and oxygen during the fabrication process as well as operation time where ambient air is present, trap passivation is a method that can be employed to prevent charge trap state caused by the non-uniformity at the active cell interlayer surface. In this paper, we applied 3 levels of tetraethyl orthosilicate (TEOS) concentration into perovskite active layer in order to find which level of concentration brings out the best Voc, Isc and Fill Factor of the perovskite solar cell. In this research, we obtained the best result with 0.3%mol of applied TEOS additive into the perovskite active layer with Voc, Isc, and FF value of 0.76 V, 3.96 mA, and 0.4563 respectively.
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