新型结构声反应器对氯苯的降解:多换能器声反应器与传统声反应器的比较

Hua-sheng Zou, Chao Zhou, Gang Lin
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引用次数: 1

摘要

声呐反应器作为一种先进的污水处理技术,在污水处理领域有着广阔的应用前景。将氯苯溶液分别在平行或正交多频超声反应器和超声浴中进行超声照射,每隔30 min对部分反应溶液进行紫外-可见分光光度计分析,测定溶液中氯苯残留量,并计算氯苯的降解率。结果表明,正交超声场对氯苯的降解率比单频率场对氯苯的降解率代数总和高10%~11%,平行场对氯苯的降解率几乎与单频率场的降解率总和相当。对比不同功率输入下的CB降解率,发现降解百分比增幅与工作功率输入成反比。在相同工作频率、功率消耗为90 w、照射时间为120 min的条件下,反应器对CB(初始浓度为50 mg/L)的降解率为10.8%,高于超声浴的降解率7.6%。
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Degradation of Chlorobenzene in Novel Configuration Sonoreactors: Comparison Between Sonoreactor with Multi Transducer and Conventional Sonoreactor
Sono-reactors have a promising future in the area of wastewater treatment as one of the advanced technologies. The solution of chlorobenzene(CB) was irradiated by ultrasound in a parallel or orthorhombic multi-frequency sono-reactor and in an ultrasonic bath, then, some reacted solution was analyzed by uv-vis spectrophotometer every 30 min to measure the remained content of chlorobenzene in the solution, and the degradation percentage of chlorobenzene was calculated. It has been found that the degradation percentage of chlorobenzene in orthorhombic ultrasonic fields was greater by 10%~11% than the algebraic sum of degradations of chlorobenzene in individual frequency field, and the degradation percentage in parallel fields was almost as same as the sum of degradation in individual frequency field. Comparing the rates of degradation of CB in different power input, it was found that the increase in amplitude of degradation percentage was inversely proportional to the operating power input. In the same operating frequency, power dissipation of 90 w, and irradiation time of 120 min, the degradation percentage of CB (initial concentration is 50 mg/L) in the reactor studied in the paper was 10.8% which was higher than the degradation percentage of 7.6% in the ultrasonic bath.
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