噻唑[2,3-d]和1,2-二噻唑[4,5-c]的新合成方法

M. T. Omar, A. A. El-Khamry, A. Youssef, S. K. Ramadan
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引用次数: 1

摘要

3-取代-5-(2-芳基-2-氧乙基)-2-硫氧基-4-氧基-1,3-噻唑烷与四磷十硫化物或与Lawesson试剂在二甲苯中的硫离子化分别得到3-取代-5-芳基-2,3-二氢[2,3-d] 1,3-噻唑-2-硫酮2a-e。然而,1f的硫代化得到3-(3-甲基苯基)-6-(4-乙基苯基)-2-硫-2,3-二氢噻唑[4,5-c]1,2-二萜3。合成的化合物的结构得到了微量分析和光谱证据的支持。并对转换路线进行了合理化分析。
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Novel synthesis of thieno[2,3-d] and 1,2-dithiino[4,5-c] Thiazoles
Thionation of 3-substituted-5-(2-aryl-2-oxoethyl)-2-thioxo-4-oxo-1,3-thiazolidines 1a-e either with tetraphosphorous decasulfide or with Lawesson's reagent in xylene affords the respective 3-substituted-5-aryl-2,3-dihydro [2,3-d] 1,3-thiazole-2-thiones 2a-e . However, thionation of 1f affords 3-(3-methylphenyl)-6-(4-ethylphenyl)-2-thio-2,3-dihydrothiazolo[4,5-c]1,2-dithin 3 . The structure of the synthesized compounds were supported by microanalytical and spectral evidence. A rationalization for the route of conversion was also given.
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