用于封装有机光伏的混合原型密封胶的演示

Minjae Kim, M. C. Clingerman, Alex W. Kawczak, P. R. Berger
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摘要

光伏(PV)技术的技术和经济可行性由三个参数决定:效率、成本和寿命。自成立以来,有机光伏(OPV)研究的主要推动力一直是实现高效率。持续的努力取得了成果,达到了10%的效率,这被认为是商业可行性的盈亏平衡点。下一个合乎逻辑的步骤是把注意力转移到生活上。通过可靠的封装提高OPV的使用寿命,提高技术可行性和经济可行性。到目前为止,重点放在封装阻隔膜上,对密封胶的研究很少;在这种有限的努力中,对现有商用密封剂进行测试是大趋势。OPV封装对密封胶的要求包括兼容低成本和低温的OPV加工、轻便、灵活、透明以及热稳定性和紫外线稳定性。混合密封胶既具有无机密封胶的良好渗透性,又具有有机密封胶的柔韧性。在这篇贡献中,我们报告了新的柔性混合原型密封胶通过钙腐蚀试验的演示。密封胶可丝网印刷,灵活,可在130°C下在15分钟内固化。我们的混合密封胶的密封性能与商用硅基混合密封胶,即聚二甲基硅氧烷(PDMS)进行了比较。
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Demonstration of hybrid prototype sealant for encapsulating organic photovoltaics
Technical and economic viability of photovoltaic (PV) technology are governed by three parameters: efficiency, cost and lifetime. Since its inception, the main driver in organic photovolatics (OPV) research has been towards achieving high efficiency. Continued effort was fructified as achievement of 10 % efficiency, which was considered as a break-even point for commercial viability. Shifting of focus to lifetime is a next logical step. Increase lifetime of OPV by reliable encapsulation enhances technical feasibility and economic viability. So far, focus has been given on encapsulation barrier films, and little effort has been made on sealants; of this limited effort, the testing of existing commercial sealants is the general trend. Requirements of Sealants for OPV encapsulation include compatibility with low-cost and low-temperature OPV processing, lightness, flexibility, transparency, as well as thermal and UV stability. Hybrid sealants take advantages of good permeability of inorganic sealants and flexibility of organic sealants. In this contribution, we report on the demonstration of new flexible hybrid prototype sealants by calcium corrosion test. Sealants are screen-printable, flexible and can be cured at 130 °C in 15 minutes. Sealing capability of our hybrid sealants was compared with commercial silicone based hybrid sealant, i.e. polydimethylsiloxane (PDMS).
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