花生壳活性炭氯化锌浸渍法对染料废水的脱色研究

N. Quan, Nguyen Minh Hanh, L. Oanh
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引用次数: 0

摘要

考察了花生壳活性炭在不同接触条件下对染料废水中S3B染料(Sunfix Red 150%)的吸附能力。以ZnCl2(质量比为1:1)预浸渍原料,使所产活性炭的表面电荷增加到正电荷;而未浸渍和浸渍后的活性炭则带负电荷。最佳吸附条件为:pH为5,活性炭浓度为10 g/L,接触时间为180 min。在最佳条件下,预浸渍活性炭的吸附量最高,对S3B染料的去除率为80.2%;而其他两种活性炭的去除率约为40%。吸附过程符合Freundlich等温模型(多层吸附),未浸渍活性炭、浸渍前活性炭和浸渍后活性炭的KF吸附常数分别为0.0377、0.3314和0.0523。
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Decolorization of Dye Wastewater by Activated Carbons Produced from Peanut Shell using ZnCl2 Impregnation Method
This study assessed the adsorption capacity of different activated carbons produced from peanut shell for S3B dye (Sunfix Red 150%) present in dye wastewater under different contact conditions. The pre-impregnation of input material by ZnCl2 (weight ratio 1:1) increased surface charge of produced activated carbon to positive value; While activated carbons produced from non-impregnation and post-impregnation procedures had negative charge. The optimal adsorption conditions were at pH 5 with 10 g/L activated carbon in original dye wastewater ,  for 180 minute contacting time. Under the optimal conditions, pre-impregnated activated carbon had highest adsorption capacity, corresponding to80.2% S3B dye removal; while the two other types of activated carbons obtainedabout 40% dye removal. The adsorption process suited to Freundlich isotherm model (multilayer adsorption) with KF adsorption constants being 0.0377, 0.3314 and 0.0523 for non-, pre- and post-impregnated activated carbons, respectively.
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