高效超薄~ 25微米晶体硅太阳能电池的远程等离子体化学气相沉积

D. Sarkar, E. Onyegam, S. Saha, L. Mathew, R. Rao, M. Hilali, R. S. Smith, Dewei Xu, D. Jawarani, R. Garcia, R. Stout, A. Gurmu, M. Ainom, J. Fossum, S. Banerjee
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引用次数: 4

摘要

首次在薄晶硅金属半导体(SOM)衬底上开发了基于远程等离子体化学气相沉积(RPCVD)的c-Si/a- si异质结太阳能电池工艺。在RPCVD系统中,可以改变沉积温度、沉积速率和样品与等离子体源的距离,以尽量减少表面损伤并提高钝化质量。在脱落的~ 25µm c-Si SOM箔上制备了无本征A - si层钝化的硅异质结(HJ)电池,效率为13.4%,开路电压为645mV。通过数值模拟分析了这些器件的损耗,设计了最优器件结构并对其性能进行了预测。
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Remote plasma chemical vapor deposition for high-efficiency ultra-thin ∼25-microns crystalline Si solar cells
For the first time, a remote plasma chemical vapor deposition (RPCVD) based c-Si/a-Si heterojunction solar cell process was developed on thin crystalline silicon semiconductor-on-metal (SOM) substrate. In RPCVD systems, deposition temperature, deposition rate, and the distance of the sample from the plasma source can be varied to minimize the surface damage and enhance passivation quality. A silicon heterojunction (HJ) cell without intrinsic a-Si layer passivation was fabricated on an exfoliated ∼25µm c-Si SOM foil, with an efficiency of 13.4% and open-circuit voltage of 645mV. Losses in these devices were analyzed by numerical simulations and optimum device structure was designed and performance predicted.
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