硫代联苯酰亚胺的合成及x射线结构测定

Sulfur Letters Pub Date : 2002-01-01 DOI:10.1080/02786110215844

M. Coogan, J. Platts, R. Haigh

{"title":"硫代联苯酰亚胺的合成及x射线结构测定","authors":"M. Coogan, J. Platts, R. Haigh","doi":"10.1080/02786110215844","DOIUrl":null,"url":null,"abstract":"Thiation of N , N -biphthalimide in a search for new axially chiral ligands gave a mixture of oligothiobiphthalimides; X-ray crystallography shows that the achiral isomer of dithiodioxobiphthalimide, 1,3-dithioxo-1H-3H-[2,2 ' ]biisoindolyl-1 ' ,3 ' -dione is formed, which may imply a change in the mechanism of thiation between mono- and di-phthalimides.","PeriodicalId":22122,"journal":{"name":"Sulfur Letters","volume":"37 1","pages":"251 - 257"},"PeriodicalIF":0.0000,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Synthesis and X-ray structure determination of thionated biphthalimides\",\"authors\":\"M. Coogan, J. Platts, R. Haigh\",\"doi\":\"10.1080/02786110215844\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Thiation of N , N -biphthalimide in a search for new axially chiral ligands gave a mixture of oligothiobiphthalimides; X-ray crystallography shows that the achiral isomer of dithiodioxobiphthalimide, 1,3-dithioxo-1H-3H-[2,2 ' ]biisoindolyl-1 ' ,3 ' -dione is formed, which may imply a change in the mechanism of thiation between mono- and di-phthalimides.\",\"PeriodicalId\":22122,\"journal\":{\"name\":\"Sulfur Letters\",\"volume\":\"37 1\",\"pages\":\"251 - 257\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sulfur Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/02786110215844\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sulfur Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/02786110215844","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 2

摘要

N, N -联苯酰亚胺的硫代化在寻找新的轴向手性配体中得到了低硫代联苯酰亚胺的混合物;x射线晶体学表明，二硫代二氧苯酞亚胺形成了非手性异构体1,3-二硫代氧- 1h - 3h -[2,2 ']生物异吲哚-1 '，3 ' -二酮，这可能表明单邻苯酞亚胺与二邻苯酞亚胺之间的硫化机理发生了变化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Synthesis and X-ray structure determination of thionated biphthalimides

Thiation of N , N -biphthalimide in a search for new axially chiral ligands gave a mixture of oligothiobiphthalimides; X-ray crystallography shows that the achiral isomer of dithiodioxobiphthalimide, 1,3-dithioxo-1H-3H-[2,2 ' ]biisoindolyl-1 ' ,3 ' -dione is formed, which may imply a change in the mechanism of thiation between mono- and di-phthalimides.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Sulfur Letters

自引率

0.00%

发文量