钙钛矿前驱体摩尔浓度对太阳能电池性能的影响

N. R. Poespawati, L. Kevin, T. Abuzairi, R. P, J. Sulistianto, Rembianov
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摘要

太阳能电池是一种新兴的可再生能源,目前仍处于发展阶段。特别是近年来出现的钙钛矿基太阳能电池(PSC),显示出成为高效能源的巨大潜力。它不是最有效的,但它的效率百分比呈指数增长。在这项工作中,我们想要找到PbC12的最有效摩尔浓度。我们使用自旋镀膜和退火方法在FTO玻璃上制作材料层。这种方法非常简单,易于使用。PSC结构由6层组成,分别是FTO玻璃、电子转移材料(ETM)、钙钛矿、空穴转移材料(HTM)、碳和FTO玻璃。这个太阳能电池上的钙钛矿是活性层,当它被阳光照射时,会产生电子和空穴。活性层中前驱体粒子越多,电子空穴产生的可能性越大。该层前驱体的摩尔浓度影响其颗粒的数量,从而提高太阳能电池的性能。从改变摩尔浓度的制备结果来看,0.5M PbC12的钙钛矿基太阳能电池是最佳的摩尔浓度值,制备所需的PbC12和MAI更少,节省了更多的材料,PSC的性能最高,即0.56V Voc, 2.37mAIsc, 0.33填充因子。
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Effect of Perovskite Precursors Molarity on Solar Cell Performance
Solar cell is a very new renewable power supply and it still in the development process. Especially with the perovskite-based solar cell (PSC) which in recent year it shows a very high potential of being very efficient power. It has not been the most efficient but the increase or its efficiency percentage is exponentially increasing. In this work, we want to find the most efficient molarity for PbC12. We were using the spin coating and annealing method to make layers of material on top of FTO glass. This method is very simple and easy to use. The PSC structure consists of 6 layers, namely FTO glass, Electron Transfer Material (ETM), Perovskite, Hole Transfer Material (HTM), carbon, and FTO glass. Perovskite on this solar cell is the active layer where this layer will generate electron and hole when it is shined by sunlight. The probability of electron-hole generation will be increased by the more particle of precursors in this active layer. The molarity of precursors of this layer affects the amount of its particle and will raise the performance of the solar cell. From the fabrication results by varying the molarity, it was found that the perovskite-based solar cell with 0.5M of PbC12 is best molarity value with much less PbC12 and MAI needed to make it which save more material, and with the highest result of the performance of the PSC, namely 0.56V Voc, 2.37mAIsc, and 0.33 fill factor.
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