硫硫对水中重金属离子的吸附净化

N.S. Murzakassymova, M. A. Gavrilenko, N. Bektenov, R.M. Kudaibergenova, E.A. Baybazarova
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摘要

研究了改性活性炭的吸附性能;显示了在水体中产生铁(II, III)吸附剂的可能性,其纯水产量高达0.01 mg/l。采用亚砜作为改性剂和络合剂。迄今为止,有成千上万种吸附剂被生产出来,它们具有各种基体材料、功能分组、固定方式、容器、机械性能、造粒和其他特性。最佳吸附剂的选择取决于分配给研究人员的任务。在很大程度上,吸附剂的选择取决于微组分的性质——该组分在溶液中的存在形式、离子或分子的大小和电荷、这种形式与官能团或直接与吸附剂表面反应的能力。在选择吸附剂时,有必要考虑到浓缩方式。因此,在静态条件下吸附萃取后,吸收剂浓缩液应易于与母液分离;当在动态模式下使用时,不希望使用强溶胀吸附剂,以及吸附剂的过小分数。在联合技术中,第一步是浓缩,第二步是纯净水的质量控制,分光光度法、原子吸收光谱法(AAS)、电感耦合等离子体原子发射光谱法(NPP-ISP)、电感耦合等离子体质谱法(MS-ISP)等光谱方法可以起作用,使元素的快速定量洗脱成为可能。开发从重金属中,特别是从天然和饮用水中广泛存在的铁(II, III)阳离子中净化水的快速和简单方法是分析化学的一项重要任务。这是由于环境物体中铁的含量很高,以及过量的铁离子对人体的生物医学影响。
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SORPTION PURIFICATION OF WATER FROM HEAVY METAL IONS USING SULFOUGL
The sorption capacity of modified activated carbon is investigated; the possibility of creating a sorbent for iron (II, III) in water bodies with a purified water yield of up to 0.01 mg/l is shown. A sulfogroup was used as a modifier and a complexing agent. To date, thousands of sorbents are produced with various matrix materials, functional groupings, ways of fixing them, containers, mechanical properties, granulation and other characteristics. The choice of the optimal sorbent depends on the task assigned to the researcher. To a large extent, the choice of a sorbent is determined by the nature of the micro–component - the form of existence of this component in solution, the size and charge of an ion or molecule, the ability of this form to react with functional groups or directly with the surface of the sorbent. When choosing a sorbent, it is necessary to take into account the concentration mode. Thus, after sorption extraction under static conditions, the sorbent concentrate should be easily separated from the mother liquor; when used in dynamic mode, it is undesirable to use strongly swelling sorbents, as well as too small fractions of sorbents. In combined techniques, where the first step is concentration, and the second is quality control of purified water, spectroscopic methods such as spectrophotometry, atomic absorption spectroscopy (AAS), atomic emission spectroscopy with inductively coupled plasma (NPP-ISP), mass spectrometry with inductively coupled plasma (MS-ISP) can act, the possibility of rapid and quantitative elution of elements. The development of express and simple methods of water purification from heavy metals, in particular, from the widespread iron (II, III) cation in natural and drinking waters is an important task of analytical chemistry. This is due to the high prevalence of iron in environmental objects and the biomedical effect of an excess of its ions on the human body.
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