含碳掺杂TiO2纳米颗粒的玻璃微珠连续流动环形光反应器在实验室规模下光催化降解过氯乙烯

H. Kazemi, M. Rabbani, Haniye Kashafroodi, Hossin Kazemi
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引用次数: 1

摘要

本研究采用固定床连续流管式光反应器,研究了气相光催化降解过氯乙烯的量。光反应器由一个圆柱形玻璃管组成,管内填充涂有TiO2纳米粒子、TiO2掺杂碳(TiO2- c)的玻璃珠。这些纳米颗粒采用溶胶-凝胶法制备,并采用溶胶-凝胶浸镀技术沉积在玻璃微珠上。利用x射线衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)和漫反射光谱(DRS)对合成材料进行表征。通过紫外光照射,考察了相对湿度、停留时间、PCE浓度等不同参数对光催化降解过程的影响,以达到最高的降解效率。采用气相色谱-质谱联用仪(GC-MS)对PCE的降解过程和副产物进行了监测和鉴定。在最佳实验条件下,研究并比较了TiO2、TiO2- c的光催化活性。结果表明,掺杂碳后,TiO2降解PCE的光催化活性大大提高。对于TiO2-C催化剂,在初始PCE浓度为3000 ppm、湿度为30%、停留时间为1 min的紫外线照射下,大约96%的初始PCE被降解。
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Photocatalytic degradation of Perchloroethylene by a lab-scale continuous-flow annular photoreactor packed with glass beads carbon-doped TiO2 nanoparticles
In this study, the amount of photocatalytic degradation of perchloroethylene in the gas phase was investigated by a fixed bed continuous-flow tubular photoreactor. The photoreactor consists of a cylindrical glass tube, was filled with glass beads coated with nanoparticles of TiO2, TiO2 doped carbon (TiO2-C). These nanoparticles were synthesized by the sol-gel method and deposited on glass beads using the sol-gel dip technique. X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FT-IR), and diffuse reflectance spectroscopy (DRS) were used for the characterization of synthesized materials. The effect of different parameters such as relative humidity, residence time, PCE concentration on the photocatalytic degradation process was investigated by ultraviolet irradiation to achieve the highest possible degradation efficiency. The PCE degradation and byproduct species were monitored and identified with a gas chromatography-mass spectrometer device (GC-MS). Under the optimum experimental conditions, the photocatalytic activities of TiO2, TiO2-C were investigated and compared together. The results showed that photocatalytic activity of TiO2 for degradation of PCE was extremely increased when doped with carbon. For TiO2-C catalyst, under UV irradiation (3000 ppm initial PCE concentration, 30% humidity and 1 min residence time) approximately 96% of the initial PCE was degraded.
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