活性炭负载催化剂对室内臭氧的分解

Yongquan Yin, Yan Zheng, Shuzhong He, Quan Cui
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引用次数: 2

摘要

采用浸渍法制备了活性炭负载铜、银、锰催化剂(Cu/GAC、Ag/GAC和Mn/GAC)。通过正交试验确定了最佳的制备条件,包括载金属量、煅烧温度和煅烧时间。在最佳条件下制备了各种催化剂。考察了Cu/GAC、Ag/GAC、Mn/GAC、活性炭(GAC)和分子筛(MS)对臭氧分解的催化活性。对比实验表明,Ag/GAC活性最高,是去除室内臭氧的理想催化剂。Cu/GAC、Mn/GAC和Ag/GAC的x射线衍射(XRD)表明,铜和银以原子的形式被吸附在活性炭上,而锰以一氧化碳的形式存在。最后,提出了臭氧在Cu/GAC、Ag/GAC和Mn/GAC表面分解的可能机理。
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Decomposion of Indoor Ozone on Activated Carbon-Supported Catalysts
Activated carbon-supported copper, silver and manganese catalysts (Cu/GAC, Ag/GAC and Mn/GAC) were prepared by impregnation. Orthogonal experiments were conducted to find the optimum preparation conditions including metal loading, calcination temperature and calcination time. Each catalyst was prepared under the optimum conditions. Catalytic activities for decomposition of ozone of Cu/GAC, Ag/GAC, Mn/GAC, activated carbon (GAC) and molecular sieve (MS) were investigated. The comparison experiments showed that Ag/GAC had the highest activity and was an ideal catalyst to remove indoor ozone. X-ray diffraction (XRD) of Cu/GAC, Mn/GAC and Ag/GAC showed that copper and silver were loaded as atoms on activated carbon, while manganese was present as the monoxide. Finally, possible mechanisms for ozone decomposition on the surface of Cu/GAC, Ag/GAC and Mn/GAC are proposed.
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