新型壳聚糖包覆CdS复合材料对甲基橙的吸附及可见光催化脱色

R. Jiang, Hua-yue Zhu, Xiaodong Li
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引用次数: 2

摘要

在温和条件下,采用仿生合成方法制备了壳聚糖封顶CdS (CdS/CS)复合材料。采用该新型复合催化剂进行了甲基橙(MO)的可见光脱色。考察了催化剂用量、初始染料浓度、辐照时间、pH值、无机离子和催化剂重复使用对脱色效果的影响。发现光催化脱色动力学遵循伪一级反应。紫外可见光谱分析表明,CdS/CS复合催化剂对染料的光催化脱色实际上是染料吸附和降解的协同作用。结果表明,CdS/CS光催化剂在吸附光催化脱除水中有机废物方面具有潜在的应用前景。
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Adsorption and Visible Light Photocatalytic Decolorization of Methyl Orange Using Innovative Chitosan Capped CdS Composite
Chitosan capped CdS (CdS/CS) composite was prepared by biomimetic synthesis method under mild conditions. Visible light photocatalytic decolorization of Methyl Orange (MO) was carried out by employing this innovative composite catalyst. Effect of catalyst amount, initial dye concentration, irradiation time, pH value, inorganic ions and reuse of the catalyst on decolorization was investigated. The kinetics of photocatalytic decolorization was found to follow a pseudo-first order reaction. UV-Vis spectra were analyzed to indicate that photocatalytic decolorization of the dye by CdS/CS composite catalyst was the synergistic effect of adsorption and degradation of dye actually. Results suggested that photocatalyst of CdS/CS is suitable for potential applications in organic waste removal from water by adsorption and photocatalysis.
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