一种新型异质结CuWO4/g-C3N4光催化剂在可见光下去除有机污染物

D. Dang, S. Le, Hai Huy Nguyen
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摘要

本研究采用简便的构建方法合成了一系列CuWO4/g-C3N4复合材料。采用XRD、SEM、SEM- eds、FT-IR、UV-DRS等技术对复合材料的结构特征进行了表征。考察了CuWO4/g-C3N4纳米复合材料在可见光下降解亚甲基蓝(MB)的光催化性能。结果表明,CuWO4质量比为10%的CuWO4/g-C3N4复合材料在80分钟的光降解过程中对MB的降解效率最高(89%),符合准一级动力学。这些结果清楚地表明,z型CuWO4/g-C3N4异质结的形成通过促进电子-空穴对的快速分离和增强氧化还原能力,显著提高了光催化效率。此外,经过4次循环后,光降解效率仍保持在85%以上,表明催化剂的稳定性。
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A Novel Heterojunction CuWO4/g-C3N4 Photocatalyst for Removal of Organic Pollutant under Visible Light Irradiation
In this study, a series of CuWO4/g-C3N4 composites were synthesized using a facile construction method. The structural characteristics of the composites were examined using various techniques, including XRD, SEM, SEM-EDS, FT-IR, and UV–DRS. The photocatalytic performance of the CuWO4/g-C3N4 nanocomposites was evaluated in the degradation of methylene blue (MB) under visible light irradiation. The findings revealed that the CuWO4/g-C3N4 composite with a mass ratio of 10% CuWO4 displayed the highest efficiency (89%) in degrading MB during an 80-minute photodegradation process, which was consistent with the pseudo-first-order kinetics. These results clearly demonstrate that the formation of a Z-scheme CuWO4/g-C3N4 heterojunction significantly improves the photocatalytic efficiency by promoting rapid separation of electron-hole pairs and enhancing the redox capability. Additionally, the photodegradation efficiency remained above 85% even after four cycles, suggesting the stability of the catalyst.
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