二氧化钛/二氧化硅纳米复合干凝胶的光催化研究

Muhammad Yaseen, Z. Shah, R. C. Veses, S. Dias, E. Lima, G. S. Reis, J. C. Vaghetti, W. S. Alencar, K. Mehmood
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引用次数: 20

摘要

为了促进反应后产物的分离,人们提出在光催化过程中使用二氧化钛-二氧化硅材料作为传统TiO2催化剂的替代品。然而,尽管在该领域进行了大量的研究,但TiO2/SiO2混合氧化物光催化活性的机理尚不清楚。采用溶胶-凝胶法制备了二氧化钛-二氧化硅纳米复合干凝胶。本文研究了二氧化钛-二氧化硅纳米复合静电凝胶的合成及其光催化性能。以HCl和NH4OH为催化剂,将TEOS:TTIP:MtOH:DIW的摩尔比分别保持在1:1:6 . 14,制备了纳米复合干凝胶。制备后用FTIR、XRD、UV和LLS对其进行了表征。所有这些技术都显示了二氧化钛干凝胶的无定形性质。
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Photocatalytic studies of tio2/sio2 nanocomposite xerogels
The use of titania-silica materials in photocatalytic processes has been proposed as an alternative to the conventional TiO2 catalysts, in order to facilitate the separation of products after the reaction. However, despite the large number of research in this field, the mechanism governing the photocatalytic activity of the mixed TiO2/SiO2 oxides is not clear. Titania-Silica nanocomposite xerogels were prepared by sol-gel method. This work has been used to describe the synthesis and the photocatalytic properties of TiO2-SiO2 nanocomposite xerogel. The nanocomposite xerogels were prepared by keeping the molar ratio of TEOS:TTIP:MtOH:DIW at 1: 1:6:14 respectively and the catalysts used were HCl and NH4OH. After the preparation xerogels were characterized by FTIR, XRD, UV and LLS. All these techniques show the amorphous nature of Titania-silica xerogel.
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