氨基功能化金属-有机骨架固相萃取法测定大米样品中的镉

Mohammad Abbaszadeh, A. Miri, Mohammad Reza Rezaei Kahkha
{"title":"氨基功能化金属-有机骨架固相萃取法测定大米样品中的镉","authors":"Mohammad Abbaszadeh, A. Miri, Mohammad Reza Rezaei Kahkha","doi":"10.24200/amecj.v5.i03.208","DOIUrl":null,"url":null,"abstract":"In this study, the amino-functionalized metal-organic framework (NH2-MOFs) was used as an adsorbent for the extraction of cadmium in rice samples based on the pipette tip solid phase extraction (PT-SPE) before determined by the flame absorption spectrometry (F-AAS). The pH of the sample solution, initial concentration of the cadmium, the volume of the sample, elution ‎conditions, and the amount of adsorbent on the recovery of the cadmium were investigated and ‎optimized. The results showed that the best extraction efficiency of cadmium was obtained at pH 5.0, 2500.0 µL of cadmium solution, and 20.0 ‎µL of HCl (10% V/V) ‎ as eluent solvent. First, the cooking rice was transferred to a beaker and hydrochloric acid/nitric acid was added to it as a digestion process before analysis by the PT-SPE procedure. The limit of detection of this method was found to be 0.03 µg L-1 with a relative standard deviation of ≤ 2.5 % (for seven replicate analyses of 50 µg L-1 of cadmium). The linear and dynamic ranges were achieved at 0.3 -14.5 µg L-1 and 0.3 -150 µg L-1, respectively.  The adsorption capacity of sorbent and enrichment factor was 175 mg g-1 and 125 folds, respectively.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":"34 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Determination of cadmium in rice samples using amino-functionalized metal-organic framework by a pipette tip solid phase extraction\",\"authors\":\"Mohammad Abbaszadeh, A. Miri, Mohammad Reza Rezaei Kahkha\",\"doi\":\"10.24200/amecj.v5.i03.208\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, the amino-functionalized metal-organic framework (NH2-MOFs) was used as an adsorbent for the extraction of cadmium in rice samples based on the pipette tip solid phase extraction (PT-SPE) before determined by the flame absorption spectrometry (F-AAS). The pH of the sample solution, initial concentration of the cadmium, the volume of the sample, elution ‎conditions, and the amount of adsorbent on the recovery of the cadmium were investigated and ‎optimized. The results showed that the best extraction efficiency of cadmium was obtained at pH 5.0, 2500.0 µL of cadmium solution, and 20.0 ‎µL of HCl (10% V/V) ‎ as eluent solvent. First, the cooking rice was transferred to a beaker and hydrochloric acid/nitric acid was added to it as a digestion process before analysis by the PT-SPE procedure. The limit of detection of this method was found to be 0.03 µg L-1 with a relative standard deviation of ≤ 2.5 % (for seven replicate analyses of 50 µg L-1 of cadmium). The linear and dynamic ranges were achieved at 0.3 -14.5 µg L-1 and 0.3 -150 µg L-1, respectively.  The adsorption capacity of sorbent and enrichment factor was 175 mg g-1 and 125 folds, respectively.\",\"PeriodicalId\":7797,\"journal\":{\"name\":\"Analytical Methods in Environmental Chemistry Journal\",\"volume\":\"34 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-09-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Methods in Environmental Chemistry Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24200/amecj.v5.i03.208\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Methods in Environmental Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24200/amecj.v5.i03.208","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

本研究以氨基功能化金属有机骨架(NH2-MOFs)为吸附剂,采用移液头固相萃取法(PT-SPE)萃取大米样品中的镉,并用火焰吸收光谱法(F-AAS)测定镉的含量。考察了样品溶液的pH值、镉的初始浓度、样品体积、洗脱条件和吸附剂用量对镉回收率的影响,并进行了优化。结果表明,在pH 5.0、2500.0µL镉溶液、20.0µL HCl (10% V/V)为洗脱溶剂的条件下,镉的提取率最高。首先,将大米转移到烧杯中,加入盐酸/硝酸作为消化过程,然后进行PT-SPE分析。该方法的检出限为0.03µg L-1,相对标准偏差≤2.5%(对50µg L-1的镉进行7次重复分析)。线性和动态范围分别为0.3 -14.5µg L-1和0.3 -150µg L-1。吸附剂和富集因子的吸附量分别为175 mg g-1和125倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Determination of cadmium in rice samples using amino-functionalized metal-organic framework by a pipette tip solid phase extraction
In this study, the amino-functionalized metal-organic framework (NH2-MOFs) was used as an adsorbent for the extraction of cadmium in rice samples based on the pipette tip solid phase extraction (PT-SPE) before determined by the flame absorption spectrometry (F-AAS). The pH of the sample solution, initial concentration of the cadmium, the volume of the sample, elution ‎conditions, and the amount of adsorbent on the recovery of the cadmium were investigated and ‎optimized. The results showed that the best extraction efficiency of cadmium was obtained at pH 5.0, 2500.0 µL of cadmium solution, and 20.0 ‎µL of HCl (10% V/V) ‎ as eluent solvent. First, the cooking rice was transferred to a beaker and hydrochloric acid/nitric acid was added to it as a digestion process before analysis by the PT-SPE procedure. The limit of detection of this method was found to be 0.03 µg L-1 with a relative standard deviation of ≤ 2.5 % (for seven replicate analyses of 50 µg L-1 of cadmium). The linear and dynamic ranges were achieved at 0.3 -14.5 µg L-1 and 0.3 -150 µg L-1, respectively.  The adsorption capacity of sorbent and enrichment factor was 175 mg g-1 and 125 folds, respectively.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.10
自引率
0.00%
发文量
0
期刊最新文献
Determine methylene blue based on carbon paste electrode modified with nanoparticles of nickel oxide-nitrogen carbon quantum dots and carbon structures by cyclic voltammetry A review: Exploratory analysis of recent advancement in green analytical chemistry application the Determination and evaluation of trace elements in the blood of radiography workers using graphite furnace atomic absorption spectrometry Chromium desalinization using novel chitosan functionalized iron oxide- biochar composites: Analysis, synthesis, characterization and adsorption performance Solid phase-fabrication of multi-walled carbon nanotubes and their derivatives for efficient extraction and analysis of Bismarck Brown-Y Dye from aqueous solution
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1