电接触表面保护用纳米复合薄膜

S. Noel, D. Alamarguy, F. Houzé, A. Benedetto, P. Viel, S. Palacin, N. Izard, P. Chenevier
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引用次数: 5

摘要

对可靠性、恶劣环境下的操作和电触点小型化的需求不断增加,证明了对完全创新涂层的研究是合理的。这种薄膜需要许多特殊的性能,如适当的传导和机械性能。这里报道的方法是基于结合聚合物基质和导电电荷的想法。聚合物基体的选择是为了抵抗机械降解,而电荷允许良好的导电性。本文介绍了通过将碳纳米管(CNT)网络与氟化聚合物薄层相结合获得的第一个结果。一些表征技术,如XPS, FT-IR和拉曼光谱已经允许控制的各个步骤的细化过程。薄膜被沉积在铜箔上,下面是镍层,最后是电沉积金层。对几种基质进行了研究。研究了这些薄膜在球平面接触结构下的性能:首先,电学和力学特性显示出低的接触电阻和摩擦系数。碳纳米管网络的影响在宏观和微观两方面进行了研究。
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Nanocomposite thin films for surface protection in electrical contact applications
Increased demands on reliability, operations in harsh environments and miniaturisation of electrical contacts, justify research on totally innovating coatings. Such films require many specific properties such as proper conduction and mechanical behaviour. The approach reported here is based on the idea of associating a polymer matrix and a conducting charge. The polymer matrix was chosen to resist mechanical degradation while the charge allows good conductivity. The first results obtained by associating a carbon nanotube (CNT) network to a fluorinated polymer thin layer are presented here. Several characterisation techniques such as XPS, FT-IR and Raman spectroscopy have allowed the control of the various steps of the elaboration process. Films were deposited on cuprous coupons with a nickel underlayer and an electrodeposited gold final layer. Several matrixes were studied. The properties of these thin films were investigated in a ball plane contact configuration: first electrical and mechanical characterisations show low values of contact resistance and friction coefficient. The CNT network influence is investigated both at a macroscopic scale and at a microscopic one.
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