Synthesis and Electrical properties of polyaniline yielded in nickel sulfate salt

Santos Stefany C. S. dos, Dias Leonay E. S., João H. Pinton, Rosimara P. Toledo, D. R. Huanca
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Abstract

Polyaniline (PANI) samples were synthesized onto platinum wire in HCl-based aqueous solution containing low amounts of nickel sulfate. The structural analysis of them shows increasing densification of its porous structure insofar the amount of this salt increases. This fact leads to the enhancement of its total conductance, consequently, improves the current flow. In addition, the impedance electrochemical spectroscopy shows that also the capacitances and resistances associated to the platinum/PANI/electrolyte system also undergoes modification so that the current-potential curves exhibit an increasing hysteresis, making this material an excellent candidate to be used in energy storage devices or supercapacitors.
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硫酸镍盐中聚苯胺的合成及其电学性能
在含少量硫酸镍的盐酸水溶液中,在铂丝上合成聚苯胺(PANI)样品。结构分析表明,随着盐含量的增加,其多孔结构致密化程度增大。这一事实导致其总电导的增强,从而改善了电流。此外,阻抗电化学谱分析表明,与铂/聚苯胺/电解质体系相关的电容和电阻也发生了变化,使得电流-电位曲线呈现出越来越大的滞后,使该材料成为储能装置或超级电容器的优秀候选者。
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