Development of Low-temperature Sintering Materials for Bare Cu lead-frame

Kazuki Fukazawa, N. Mizumura, S. Saito, K. Sasaki
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Abstract

This paper will discuss the fundamental study on nano-silver die attach newly developed with a unique approach using MO (Metallo-organic) technology.Nano-silver provides a low-temperature sintering capability. The nano-silver die attach shows high thermal performance and strong adhesion to Ag and Au plated dies and lead-frame with the metallic bond without pressure during the curing process.In addition, resin reinforcing technology and lowering modulus technology have been developed to improve the mechanical properties. By adding special epoxy resins to the die attach, the porous area is filled with the resin and the sintered structure is reinforced. Additionally, the reliability can be further improved by thermoplastic resin particles. The modulus and the stress caused by the CTE mismatch between the die and lead-frame can be lowered by adding the resin particles to the die attach.To meet the requirement for applications without Ag or Au plated Cu lead-frame, nano-silver die attach for bare Cu application have newly been developed. The addition of a special additive is effectively establish metallic bonding between the nano-silver particles and bare Cu lead-frame because the additive removes the oxide layer on the surface of Cu lead-frame. By adjusting the amount of epoxy and thermoplastic resin, adhesion strength on the bare Cu lead-frame can be more improved. The fundamental investigation for the mechanism and the reliability test results in the molded package will also be discussed in this study.
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裸铜铅框架低温烧结材料的研制
本文讨论了利用MO(金属有机)技术,以独特的方式开发的纳米银贴片的基础研究。纳米银提供了低温烧结能力。在固化过程中,纳米银焊条与镀银、镀金的焊条和铅框之间的金属粘结无压力,具有较高的热工性能和很强的附着力。此外,还开发了树脂增强技术和降低模量技术来改善材料的力学性能。通过在模具附着物中加入特殊的环氧树脂,使多孔区域被树脂填充,增强烧结结构。此外,热塑性树脂颗粒可以进一步提高可靠性。通过在模具附件中添加树脂颗粒,可以降低模具与引线框架之间CTE不匹配引起的模量和应力。为了满足无银或无金镀铜引线框架应用的需要,新开发了用于裸铜应用的纳米银贴片。特殊添加剂的加入可以有效地去除铜铅框架表面的氧化层,从而使纳米银粒子与裸铜铅框架之间建立起金属结合。通过调节环氧树脂和热塑性树脂的用量,可以进一步提高裸铜引线骨架的附着强度。本研究还将讨论模制包装的机理和可靠性试验结果的基础研究。
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