Structural Analysis of the Interface of Contact Melting between AMg6 and Zn-Based Alloys

E. A. Batalova, L. V. Kamaeva, I. V. Shutov, M. N. Korolev, M. D. Krivilev
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Abstract

We study the processes of the contact melting of AMg6 alloy with a solid Zn–Cu–Al solder and a model Zn–Al alloy, as well as the structure of the contact-melting zone. Sample preparation is carried out in two stages. In the first stage, the solder is mechanically applied (tinned) to the surface of AMg6 plates, and in the second stage, the obtained composite samples are subjected to heat treatment, varying the holding time in the liquid state. According to metallographic analysis, X-ray structural analysis, and differential scanning calorimetry, active interaction between Zn and Al occurs already at the tinning stage, leading to the formation of a developed morphology in the joint area. The presence of copper in the HTS-2000 solder decreases the melting temperature of the Zn–Al alloy by 30–40°C and improves the conditions of contact interaction with the AMg6 matrix. Active zinc diffusion ensures the formation of an extensive melting zone during heat treatment. Regions rich in zinc, upon crystallization, contain the intermetallic phase Zn5Cu, which hinders the formation of intermetallics based on the ZnMg system, preventing embrittlement of the contact zone.

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AMg6 与锌基合金接触熔化界面的结构分析
摘要 我们研究了 AMg6 合金与固体 Zn-Cu-Al 焊料和模型 Zn-Al 合金的接触熔化过程,以及接触熔化区的结构。样品制备分两个阶段进行。在第一阶段,将焊料以机械方式涂抹(镀锡)到 AMg6 板表面;在第二阶段,对获得的复合样品进行热处理,改变液态下的保温时间。根据金相分析、X 射线结构分析和差示扫描量热法,锌和铝在镀锡阶段就已经发生了积极的相互作用,从而在接合区域形成了发达的形态。HTS-2000 焊料中铜的存在使锌铝合金的熔化温度降低了 30-40°C,并改善了与 AMg6 基体接触相互作用的条件。活跃的锌扩散确保了在热处理过程中形成广泛的熔化区。结晶后的富锌区域含有金属间相 Zn5Cu,这阻碍了基于 ZnMg 系统的金属间化合物的形成,防止了接触区的脆化。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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