Effect of Electron Irradiation on the Optical Properties of Zinc Oxide Powder Modified with Magnesium Oxide Nanoparticles

M. M. Mikhailov, V. V. Neshchimenko, S. A. Yuriev, A. N. Lapin, V. A. Goronchko, A. N. Dudin, V. Yu. Yurina
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Abstract

The effect of modifying ZnO powders with MgO nanoparticles (with a concentration of 0.1–10 wt %) on their diffuse reflectance spectra in the region of 0.2–2.5 μm before and after irradiation with 30 keV electrons was studied. Modification of ZnO powder was carried out by MgO nanopowder with a concentration from 0.1 to 10 wt % using a solid-state method at a heating temperature of 650°C. X-ray diffraction analysis showed that with this modification method there is no formation of additional phases. It was shown that zinc oxide structure symmetry belongs to the P 63mc space group; magnesium oxide, to the Fm–3m space group. The spectral reflectance of such powders in the visible region is over 90%. Under irradiation of original and modified ZnO powders, as well as the MgO nanopowder, by 30 keV electrons, a decrease in their reflectance is recorded in the entire studied region of the spectrum. It was established that modification with MgO nanoparticles at a concentration of 3 wt % leads to an increase in radiation resistance by a factor of 1.32 compared to unmodified samples. This effect is determined by the sink of radiation defects on the large specific surface area of nanoparticles.

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电子辐照对氧化镁纳米粒子修饰的氧化锌粉末光学特性的影响
摘要 研究了氧化镁纳米颗粒(浓度为 0.1-10 wt %)对氧化锌粉末在 30 keV 电子辐照前后 0.2-2.5 μm 区域漫反射光谱的影响。在加热温度为 650°C 的条件下,采用固态法对氧化锌粉末进行了改性,改性时氧化镁的浓度为 0.1 至 10 wt %。X 射线衍射分析表明,这种改性方法不会形成额外的相。结果表明,氧化锌的结构对称性属于 P 63mc 空间群;氧化镁属于 Fm-3m 空间群。这种粉末在可见光区域的光谱反射率超过 90%。在 30 keV 电子辐照原始和改性氧化锌粉末以及氧化镁纳米粉体时,它们在整个光谱研究区域的反射率都会下降。结果表明,与未经改性的样品相比,使用 3 重量百分比浓度的氧化镁纳米粒子进行改性可使抗辐射能力提高 1.32 倍。这种效应是由纳米粒子的大比表面积上的辐射缺陷沉降决定的。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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