Activation of ultra-fine steel slag and ground granulated blast furnace slag in alkaline waste solutions via phosphogypsum and calcium carbide slag

IF 7.4 1区工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Construction and Building Materials Pub Date : 2024-11-30 DOI:10.1016/j.conbuildmat.2024.139333

Rui Guo , Caihong Xue , Qiu Li , Weichao Guo , Huimin Pan , Qingxin Zhao

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引用次数: 0

Abstract

This study expands the ways of utilizing multiple solid wastes. The pH value of SRL (soda residue liquid) closely matches that of the cement pore solution, making it a viable substitute for tap water in mixing. Purified PG (phosphogypsum) can serve as an alternative to traditional sulfate activators. CS (calcium carbide slag), currently serves as a widely utilized alkaline activator. PG and CS synergistically activate GGBFS (ground granulated blast furnace slag) in the presence of SS (steel slag) within the SRL environment. A synergistic effect is observed between SS and GGBFS. The test results demonstrate that the composite system achieves a 28-day strength of up to 60 MPa. The effect of SS content on the hydration kinetics, setting time, compressive strength was investigated. To elucidate the role of SS and PG in the reaction, the hydration products were characterized with TGA, XRD and SEM-EDS. The results suggest that the Cl^- in SRL undergoes effective immobilization within the system, thereby filling the gel pores as Friedel’s salt (Fs) and facilitating the formation of a dense structure. Q-XRD coupled with TGA was utilized to analyze the changes in crystalline and non-crystalline phases within the system, revealing the hydration mechanism of steel slag activated by physical, chemical, and mineral factors in an alkaline waste solution environment.

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来源期刊

Construction and Building Materials 工程技术-材料科学：综合

CiteScore

13.80

自引率

21.60%

发文量

3632

审稿时长

82 days

期刊介绍： Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.