Understanding Heat Transfer and the Role of Bed Hydrodynamics in High-Temperature Fluidized Beds

IF 3.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Industrial & Engineering Chemistry Research Pub Date : 2024-12-26 DOI:10.1021/acs.iecr.4c03348
Zeshi Chen, Han Gao, Qingjin Zhang, Ting Li, Liangliang Fu, Guangwen Xu, Dingrong Bai
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Abstract

A comprehensive understanding of heat transfer between the bed and immersed surfaces is critical for successfully designing and operating high-temperature gas–solid fluidized bed reactors. However, the impact of temperature on heat transfer, particularly in beds operating above 1000 °C, remains underexplored. This study investigates heat transfer between a fluidized bed and an immersed vertical surface over a temperature range of 300–1500 °C, with a focus on the relationship between heat transfer and bed hydrodynamics. The results indicate that below 1200 °C, the heat transfer coefficient (h0) increases gradually with temperature, with radiative heat transfer contributing less than 18% to h0. Above 1200 °C, h0 exhibits an exponential increase for Al2O3 and ZrO2 particles, while it decreases for MgO particles due to enhanced interparticle forces from particle softening and agglomeration. At 1500 °C, radiative heat transfer accounts for up to 30% of the total heat transfer. Additionally, smaller particles demonstrate higher h0 but lower radiative contributions than larger particles. Increasing superficial gas velocity significantly reduces h0 below 1200 °C but has minimal impact at higher temperatures. Larger beds reduce wall confinement effects, enhancing particle mixing and subsequently increasing h0. A comparison of the experimental data with predictions from existing correlations reveals their inadequacy across the studied temperature range. To address this, a new empirical correlation is proposed to improve accuracy for predicting heat transfer in high-temperature fluidized beds.

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了解高温流化床的传热及床层流体力学的作用
全面了解床层和浸入表面之间的传热对于成功设计和操作高温气固流化床反应器至关重要。然而,温度对传热的影响,特别是在1000°C以上的床层中,仍然没有得到充分的研究。本研究研究了300-1500°C温度范围内流化床与浸入垂直表面之间的传热,重点研究了传热与床流体力学之间的关系。结果表明:在1200℃以下,传热系数(h0)随温度的升高而逐渐增大,其中辐射传热对h0的贡献小于18%;在1200°C以上,Al2O3和ZrO2颗粒的h0呈指数增长,而MgO颗粒的h0则因颗粒软化和团聚产生的颗粒间力增强而下降。在1500℃时,辐射传热占总传热的30%。此外,较小的颗粒比较大的颗粒表现出更高的热值,但辐射贡献较低。在1200°C以下,增加表面气速可以显著降低h0,但在更高温度下影响最小。较大的床层减少了壁面约束效应,增强了颗粒混合,随后增加了温度。实验数据与现有相关性预测的比较揭示了它们在研究温度范围内的不足之处。为了解决这一问题,提出了一种新的经验关联,以提高高温流化床传热预测的准确性。
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来源期刊
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research 工程技术-工程:化工
CiteScore
7.40
自引率
7.10%
发文量
1467
审稿时长
2.8 months
期刊介绍: ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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