Zeshi Chen, Han Gao, Qingjin Zhang, Ting Li, Liangliang Fu, Guangwen Xu, Dingrong Bai
{"title":"Understanding Heat Transfer and the Role of Bed Hydrodynamics in High-Temperature Fluidized Beds","authors":"Zeshi Chen, Han Gao, Qingjin Zhang, Ting Li, Liangliang Fu, Guangwen Xu, Dingrong Bai","doi":"10.1021/acs.iecr.4c03348","DOIUrl":null,"url":null,"abstract":"A comprehensive understanding of heat transfer between the bed and immersed surfaces is critical for successfully designing and operating high-temperature gas–solid fluidized bed reactors. However, the impact of temperature on heat transfer, particularly in beds operating above 1000 °C, remains underexplored. This study investigates heat transfer between a fluidized bed and an immersed vertical surface over a temperature range of 300–1500 °C, with a focus on the relationship between heat transfer and bed hydrodynamics. The results indicate that below 1200 °C, the heat transfer coefficient (<i>h</i><sub>0</sub>) increases gradually with temperature, with radiative heat transfer contributing less than 18% to <i>h</i><sub>0</sub>. Above 1200 °C, <i>h</i><sub>0</sub> exhibits an exponential increase for Al<sub>2</sub>O<sub>3</sub> and ZrO<sub>2</sub> particles, while it decreases for MgO particles due to enhanced interparticle forces from particle softening and agglomeration. At 1500 °C, radiative heat transfer accounts for up to 30% of the total heat transfer. Additionally, smaller particles demonstrate higher <i>h</i><sub>0</sub> but lower radiative contributions than larger particles. Increasing superficial gas velocity significantly reduces <i>h</i><sub>0</sub> below 1200 °C but has minimal impact at higher temperatures. Larger beds reduce wall confinement effects, enhancing particle mixing and subsequently increasing <i>h</i><sub>0</sub>. A comparison of the experimental data with predictions from existing correlations reveals their inadequacy across the studied temperature range. To address this, a new empirical correlation is proposed to improve accuracy for predicting heat transfer in high-temperature fluidized beds.","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"32 1","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1021/acs.iecr.4c03348","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
A comprehensive understanding of heat transfer between the bed and immersed surfaces is critical for successfully designing and operating high-temperature gas–solid fluidized bed reactors. However, the impact of temperature on heat transfer, particularly in beds operating above 1000 °C, remains underexplored. This study investigates heat transfer between a fluidized bed and an immersed vertical surface over a temperature range of 300–1500 °C, with a focus on the relationship between heat transfer and bed hydrodynamics. The results indicate that below 1200 °C, the heat transfer coefficient (h0) increases gradually with temperature, with radiative heat transfer contributing less than 18% to h0. Above 1200 °C, h0 exhibits an exponential increase for Al2O3 and ZrO2 particles, while it decreases for MgO particles due to enhanced interparticle forces from particle softening and agglomeration. At 1500 °C, radiative heat transfer accounts for up to 30% of the total heat transfer. Additionally, smaller particles demonstrate higher h0 but lower radiative contributions than larger particles. Increasing superficial gas velocity significantly reduces h0 below 1200 °C but has minimal impact at higher temperatures. Larger beds reduce wall confinement effects, enhancing particle mixing and subsequently increasing h0. A comparison of the experimental data with predictions from existing correlations reveals their inadequacy across the studied temperature range. To address this, a new empirical correlation is proposed to improve accuracy for predicting heat transfer in high-temperature fluidized beds.
期刊介绍:
ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.