Electrocoagulation with aluminum screen mesh electrodes for oil removal from oil-in-water emulsion

IF 3.9 3区 工程技术 Q3 ENERGY & FUELS Chemical Engineering and Processing - Process Intensification Pub Date : 2025-03-01 Epub Date: 2025-01-21 DOI:10.1016/j.cep.2025.110188
Marcelly da Conceição Thomes , Igor Gomes da Silva , André Lucas Ribeiro da Silva Loures , José Rafael Capua Proveti , Cleocir José Dalmaschio , Edson C. Passamani , Paulo Sérgio da Silva Porto , Eduardo Perini Muniz
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Abstract

Concentric cylindrical mesh screen electrodes were effectively used in the electrocoagulation (EC) method to treat machine oil effluents in a static batch system. A 3² experimental design was used with electric voltage (Va) and polarity inversion time (tpi) as input variables. Therefore, this work focused on the optimization of power consumption, electrode mass loss, oil content, and turbidity, maintaining pH within international standards. Monitoring pH evolution provided insights into the EC kinetics. This innovative geometry achieved a low energy consumption of about (2.5 ± 0.4) W, a specific energy requirement of (2.2 ± 0.2) kWh/kg for an oil content reduction of (91 ± 4) % and (97 ± 2) % turbidity reduction. These results stemmed from factors like the fast kinetics described by a Boltzmann sigmoidal function and the lack of a passivation layer to increase power consumption. Therefore, our results bring a strong contribution to treatments in static batch processes of oil emulsions in effluents.

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用铝网电极电凝法去除水包油乳化液中的油
同心圆柱形筛网电极有效地应用于电絮凝(EC)法处理静态批处理系统中的机床废水。采用3²实验设计,以电压(Va)和极性反转时间(tpi)为输入变量。因此,这项工作的重点是优化功耗、电极质量损失、含油量和浊度,使pH值保持在国际标准范围内。监测pH的演变提供了EC动力学的见解。这种创新的几何形状实现了约(2.5±0.4)W的低能耗,(2.2±0.2)kWh/kg的特定能量需求,油含量降低(91±4)%,浊度降低(97±2)%。这些结果源于诸如玻尔兹曼s型函数描述的快速动力学和缺乏钝化层以增加功耗等因素。因此,我们的研究结果对污水中油乳剂的静态间歇处理有很大的贡献。
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来源期刊
CiteScore
7.80
自引率
9.30%
发文量
408
审稿时长
49 days
期刊介绍: Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.
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