Highly sensitive H2S-LITES sensor with 80 m fiber-coupled multi-pass cell based on optical path multiplexing technology

IF 6.8 1区 医学 Q1 ENGINEERING, BIOMEDICAL Photoacoustics Pub Date : 2025-02-11 DOI:10.1016/j.pacs.2025.100699
Haiyue Sun , Ying He , Shunda Qiao , Chu Zhang , Yufei Ma
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Abstract

This paper presented a highly sensitive light-induced thermoelastic spectroscopy (LITES) sensor for detecting hydrogen sulfide (H₂S) gas. Optical path multiplexing (OPM) technology was implemented within the fiber-coupled multi-pass cell (MPC) to realize ∼ 80 m gas absorption optical path length (OPL), compensating the weak absorption coefficient of H2S in the near-infrared band. A circle-head quartz tuning fork (QTF) with resonant frequency of ∼ 9.5 kHz was adopted in the H₂S-LITES sensor to enhance the energy accumulation time and the detection ability. Compared with commercial QTF, signal-to-noise ratio (SNR) based on circle-head QTF was improved by a factor of 3.36 times. Minimum detection limit (MDL) for H2S detection was measured to be 238.8 ppb. When the integration time of the system was increased to 250 s, the MDL could be improved to 19.8 ppb.
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基于光路复用技术的高灵敏度H2S-LITES传感器,具有80 m光纤耦合多通单元
提出了一种用于检测硫化氢气体的高灵敏度光致热弹性光谱(LITES)传感器。在光纤耦合多通单元(MPC)内实现了光路复用(OPM)技术,实现了~ 80 m的气体吸收光路长度(OPL),补偿了近红外波段H2S的弱吸收系数。H₂S-LITES传感器采用谐振频率为~ 9.5 kHz的圆头石英音叉(QTF),提高了能量积累时间和检测能力。与商用QTF相比,基于圆头QTF的信噪比(SNR)提高了3.36倍。H2S检测的最低检测限(MDL)为238.8 ppb。当系统集成时间增加到250 s时,MDL可提高到19.8 ppb。
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来源期刊
Photoacoustics
Photoacoustics Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
11.40
自引率
16.50%
发文量
96
审稿时长
53 days
期刊介绍: The open access Photoacoustics journal (PACS) aims to publish original research and review contributions in the field of photoacoustics-optoacoustics-thermoacoustics. This field utilizes acoustical and ultrasonic phenomena excited by electromagnetic radiation for the detection, visualization, and characterization of various materials and biological tissues, including living organisms. Recent advancements in laser technologies, ultrasound detection approaches, inverse theory, and fast reconstruction algorithms have greatly supported the rapid progress in this field. The unique contrast provided by molecular absorption in photoacoustic-optoacoustic-thermoacoustic methods has allowed for addressing unmet biological and medical needs such as pre-clinical research, clinical imaging of vasculature, tissue and disease physiology, drug efficacy, surgery guidance, and therapy monitoring. Applications of this field encompass a wide range of medical imaging and sensing applications, including cancer, vascular diseases, brain neurophysiology, ophthalmology, and diabetes. Moreover, photoacoustics-optoacoustics-thermoacoustics is a multidisciplinary field, with contributions from chemistry and nanotechnology, where novel materials such as biodegradable nanoparticles, organic dyes, targeted agents, theranostic probes, and genetically expressed markers are being actively developed. These advanced materials have significantly improved the signal-to-noise ratio and tissue contrast in photoacoustic methods.
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