Mapping human fingerprint beyond level-3 based on an amphiphilic aggregation-induced emission luminogen and the construction of intelligent platform for personal identification

IF 6 2区 化学 Q1 CHEMISTRY, ANALYTICAL Analytica Chimica Acta Pub Date : 2025-05-22 Epub Date: 2025-03-10 DOI:10.1016/j.aca.2025.343927
Xinyi Zhao , Zixuan Wang , Haoran Liu , Siyu Yan , Zihan Liu , Yuai Duan , Tianyu Han , Tiandong Han
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Abstract

Background

Fluorescence imaging agents have been benefiting tremendously from tailor-made aggregation-induced emission (AIE) luminogens, owing to their high on-off ratio, large signal contrast, low background noise as well as the resistance to photobleaching. In the domain of fingerprint imaging, AIE luminogens are beginning to exhibit an advantage owing to the aforementioned superiorities.

Results

We present an amphiphilic benzoic-acid salicylaldehyde AIE luminogen AIE-BASB, and outline its water sensitivity, self-assembly behavior as well as fingerprint imaging properties. AIE-BASB self-assembles into nanoscale textures when fabricated into a drop-casting film but undergoes a disassembly process in response to trace water on fingertip upon physical-contacting. Owing to the biological textures on the skin, fingerprint image can be clearly recorded by AIE-BASB film, which reveals detailed microscopic features of fingerprint information ranging from level-1 to level-3. Furthermore, it allows accurate measurements of the sizes, shapes, centroids, and areas of the sweat pores, which leads the fingerprint information into the next level. In addition, we develop an intelligent system based on AIE-BASB by integrating hardware and software modules, which is capable of recording and identifying fingerprint. After inputting fingerprint segments in trial operation, this intelligent system makes identification by calculation of the categorical probability, and successfully predicts the classification of the undefined fingerprint segments, implying 100 % accuracy in fingerprint identification.

Significance

We predict that AIE-BASB may facilitate the development of new biometric technologies, which have broad applications in the domain of artificial intelligence, including machine tactility, target perception and object-machine interaction.

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基于两亲性聚集诱导发光光源的三级以上指纹图谱绘制及个人识别智能平台的构建
荧光显像剂因其高开断比、高信号对比度、低背景噪声以及耐光漂白等特点,已从定制的聚集诱导发射(AIE)发光剂中受益匪浅。在指纹成像领域,AIE发光素由于上述优势开始显示出优势。结果制备了一种两亲性的苯甲酸水杨醛AIE发光剂ae - basb,并概述了其水敏性、自组装行为和指纹成像特性。AIE-BASB在制成滴铸膜时自组装成纳米级纹理,但在物理接触时,由于指尖上的痕量水而经历了一个分解过程。由于皮肤上的生物纹理,AIE-BASB膜可以清晰地记录指纹图像,揭示了1 -3级指纹信息的详细微观特征。此外,它还可以精确测量汗孔的大小、形状、质心和面积,从而将指纹信息带入下一个层次。此外,我们开发了一个基于ae - basb的智能系统,通过硬件和软件模块的集成,实现了指纹的记录和识别。该智能系统在试运行中输入指纹片段后,通过计算分类概率进行识别,成功预测了未定义指纹片段的分类,指纹识别准确率达到100%。我们预测AIE-BASB可能会促进新的生物识别技术的发展,这些技术在人工智能领域有广泛的应用,包括机器触觉、目标感知和物机交互。
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来源期刊
Analytica Chimica Acta
Analytica Chimica Acta 化学-分析化学
CiteScore
10.40
自引率
6.50%
发文量
1081
审稿时长
38 days
期刊介绍: Analytica Chimica Acta has an open access mirror journal Analytica Chimica Acta: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Analytica Chimica Acta provides a forum for the rapid publication of original research, and critical, comprehensive reviews dealing with all aspects of fundamental and applied modern analytical chemistry. The journal welcomes the submission of research papers which report studies concerning the development of new and significant analytical methodologies. In determining the suitability of submitted articles for publication, particular scrutiny will be placed on the degree of novelty and impact of the research and the extent to which it adds to the existing body of knowledge in analytical chemistry.
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