An instant polymer “coffee”: Facilitating the dissolution of high-molecular-weight water-soluble polymers

IF 4.5 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-04-22 Epub Date: 2025-03-19 DOI:10.1016/j.polymer.2025.128300
Shiyuan Wang, Zhenghua Sun, Xiaoqin Cao, Yujun Feng, Hongyao Yin
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Abstract

Water-soluble polymers have been widely employed across various industries due to their exceptional thickening power. However, the dissolution of these high-molecular-weight polymers often encounters challenges including prolonged dissolution time, additional heating requirements, and incomplete solubilization, which result in inefficiency, energy wastage, and reduced thickening performance. Herein, an oil-based instant polymer dispersion consisting with ultra-high molecular weight polyacrylamide powder, Span-85, white oil, and nano-montmorillonite was developed to address these concerns. It was found that the dissolution rate of the polyacrylamide was significantly accelerated in brine solutions, such as saturated NaCl solution, 20 % CaCl2 solution, and simulated seawater when using this polymer dispersion. The dissolution time could be reduced by up to approximately 80 % compared to that of the traditional polymer powder. The Span-85 and white oil were found to serve as barriers between polymer particles, thereby preventing their aggregation during dissolution. In addition, the dissolution process of the suspension was examined from a microscopic perspective through multiple light scattering techniques. The key factors influencing the dissolution rate were also discussed in detail. This polymer dispersion exhibits similar characteristics to instant coffee in terms of its rapid and effective dissolution properties, which not only conserves heating energy but also improves efficiency. With these advantages, the oil-based polymer dispersion is promising to act as high efficiency and sustainable solution for large scale polymer dissolution in industrial practice.

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速溶聚合物“咖啡”:促进高分子量水溶性聚合物的溶解
水溶性聚合物由于其特殊的增稠能力已广泛应用于各个行业。然而,这些高分子量聚合物的溶解通常会遇到一些挑战,包括溶解时间延长、额外的加热要求和不完全的增溶,从而导致效率低下、能源浪费和增稠性能降低。为了解决这些问题,研究人员开发了一种由超高分子量聚丙烯酰胺粉末、斯潘-85、白油和纳米蒙脱土组成的油基速溶聚合物分散体。实验发现,在饱和NaCl溶液、20% CaCl2溶液和模拟海水中,聚丙烯酰胺的溶解速度明显加快。与传统聚合物粉末相比,溶解时间可减少约80%。研究发现,Span-85和白油可以作为聚合物颗粒之间的屏障,从而防止它们在溶解过程中聚集。此外,通过多种光散射技术从微观角度考察了悬浮液的溶解过程。并对影响溶出速率的关键因素进行了详细讨论。该聚合物分散体具有与速溶咖啡相似的快速有效溶解特性,既节省了加热能量,又提高了效率。由于这些优点,油基聚合物分散体有望在工业实践中成为高效、可持续的大规模聚合物溶解解决方案。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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