Dynamic surface tension and classical nucleation theory

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 1986-08-15 DOI:10.1063/1.451123
D. Rasmussen
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引用次数: 16

Abstract

Regular solution theory is used to develop the concentration dependence for both the equilibrium and dynamic surface tension of water–alcohol binary solutions. The equilibrium surface tensions of methanol–water, ethanol–water, and n‐propanol–water binary solutions are used to fit the parameters of the theory and the dynamic surface tension is calculated. The dynamic surface tension compares favorably with the surface tension which fits classical nucleation theory vs composition at a nucleation rate of one nuclei per cubic centimeter per second.
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动态表面张力与经典成核理论
用正则溶液理论推导了水-醇二元溶液的平衡表面张力和动态表面张力的浓度依赖性。用甲醇-水、乙醇-水和正丙醇-水二元溶液的平衡表面张力拟合理论参数,计算了动态表面张力。在成核速率为每立方厘米每秒一个核的情况下,动态表面张力与符合经典成核理论的表面张力比较有利。
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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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