Effects of surface nanocrystallization on the oxide film formed on 316LN stainless steel in a high‐temperature aqueous environment

Xudong Chen, Xin Dai, H. Qian, Bin Yang, Jiqing Zhao
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引用次数: 2

Abstract

A newly developed technology, rotationally accelerated shot peening (RASP), was used to produce the nanocrystals on the surface of 316LN stainless steel. The effect of surface nanocrystallization on the oxide film properties of the steel in a high temperature and high‐pressure aqueous environment was studied. It was found that the outer layer of the oxide film consisted of NiFe2O4 with a loose spinel structure. The inner layer distributed tiny Cr2O3 particles compactly. The oxide films that grew on the RASP‐treated 316LN showed thicker and denser with higher corrosion resistance than on the as‐received steel. The nanostructures produced by RASP enhanced the formation of the superior oxide film. However, the deformation defects caused by RASP were harmful to the corrosion resistance. The results in this paper provide an easy way to enhance the corrosion resistance of the steel served in a high‐temperature aqueous environment.
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表面纳米化对高温水环境下316LN不锈钢氧化膜形成的影响
采用旋转加速喷丸强化(RASP)技术在316LN不锈钢表面制备纳米晶。研究了高温高压水环境下表面纳米化对钢氧化膜性能的影响。结果表明,氧化膜外层由具有松散尖晶石结构的NiFe2O4组成。内层致密地分布着细小的Cr2O3颗粒。在经过RASP处理的316LN上生长的氧化膜比未处理的钢更厚、更致密,具有更高的耐腐蚀性。RASP制备的纳米结构促进了优质氧化膜的形成。然而,RASP引起的变形缺陷不利于其耐蚀性。本文的研究结果为提高钢在高温水环境中的耐蚀性提供了一种简单的方法。
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